Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock

This study deals with organic matter in chalky marls of the Wadi Shallala Formation in northern Jordan. We report geochemical analyses (Total organic carbon, programmed pyrolysis, bitumen extraction, and pyrolysis�gas chromatography) for the chalky marls from 17 samples to provide information on t...

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Main Authors: Hakimi, M.H., Gharib, A.F., Alqudah, M., Ahmed, A., Hatem, B.A., Mustapha, K.A., Abidin, N.S.Z., Lashin, A., Yelwa, N.A., Alqubalee, A.M.
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Published: Elsevier Ltd 2022
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85121975181&doi=10.1016%2fj.jseaes.2021.105040&partnerID=40&md5=94b742dfe6a2e9aff5992f93fe2a8cf0
http://eprints.utp.edu.my/28630/
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spelling my.utp.eprints.286302022-03-07T10:11:01Z Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock Hakimi, M.H. Gharib, A.F. Alqudah, M. Ahmed, A. Hatem, B.A. Mustapha, K.A. Abidin, N.S.Z. Lashin, A. Yelwa, N.A. Alqubalee, A.M. This study deals with organic matter in chalky marls of the Wadi Shallala Formation in northern Jordan. We report geochemical analyses (Total organic carbon, programmed pyrolysis, bitumen extraction, and pyrolysis�gas chromatography) for the chalky marls from 17 samples to provide information on the quantity, quality, the thermal maturity of the organic matter, their potential as petroleum source rocks. The chalky marl samples contain a significant amount of total organic carbon (TOC, max = 6.53) and hydrogen index (HI) ranging from 300 to 702 mg HC/g TOC. The organic facies are mainly Types-II and -I kerogen with a potential to generate high amounts of oil. The dominance of such kerogen is consistent with significant amounts of fluorescent alginite macerals, observed under ultraviolet light microscopy. These organic facies are also confirmed by the Py-GC investigation, showing sulfur-rich Type II-S kerogen. The presence of weak carbon�sulfur (C-S) bounds in the kerogen molecules, however, suggests the generation of sulfur-rich oil at the early stages during the oil-generation window as reported by earlier works. Both geochemical maturity indicators (i.e., Tmax and PI) and the fluorescence color of the liptinite macerals indicate that the studied chalky marls in the outcropped section of the study area are still thermally immature, and maturity did not alter the organic-rich intervals to generate suitable oil for commercial production. Therefore, these organic-rich sediments in the locations having relatively deeper stratigraphic sections are likely to be promising source rocks and recommend for petroleum exploration and production in northern Jordan. © 2021 Elsevier Ltd Elsevier Ltd 2022 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85121975181&doi=10.1016%2fj.jseaes.2021.105040&partnerID=40&md5=94b742dfe6a2e9aff5992f93fe2a8cf0 Hakimi, M.H. and Gharib, A.F. and Alqudah, M. and Ahmed, A. and Hatem, B.A. and Mustapha, K.A. and Abidin, N.S.Z. and Lashin, A. and Yelwa, N.A. and Alqubalee, A.M. (2022) Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock. Journal of Asian Earth Sciences, 225 . http://eprints.utp.edu.my/28630/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description This study deals with organic matter in chalky marls of the Wadi Shallala Formation in northern Jordan. We report geochemical analyses (Total organic carbon, programmed pyrolysis, bitumen extraction, and pyrolysis�gas chromatography) for the chalky marls from 17 samples to provide information on the quantity, quality, the thermal maturity of the organic matter, their potential as petroleum source rocks. The chalky marl samples contain a significant amount of total organic carbon (TOC, max = 6.53) and hydrogen index (HI) ranging from 300 to 702 mg HC/g TOC. The organic facies are mainly Types-II and -I kerogen with a potential to generate high amounts of oil. The dominance of such kerogen is consistent with significant amounts of fluorescent alginite macerals, observed under ultraviolet light microscopy. These organic facies are also confirmed by the Py-GC investigation, showing sulfur-rich Type II-S kerogen. The presence of weak carbon�sulfur (C-S) bounds in the kerogen molecules, however, suggests the generation of sulfur-rich oil at the early stages during the oil-generation window as reported by earlier works. Both geochemical maturity indicators (i.e., Tmax and PI) and the fluorescence color of the liptinite macerals indicate that the studied chalky marls in the outcropped section of the study area are still thermally immature, and maturity did not alter the organic-rich intervals to generate suitable oil for commercial production. Therefore, these organic-rich sediments in the locations having relatively deeper stratigraphic sections are likely to be promising source rocks and recommend for petroleum exploration and production in northern Jordan. © 2021 Elsevier Ltd
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author Hakimi, M.H.
Gharib, A.F.
Alqudah, M.
Ahmed, A.
Hatem, B.A.
Mustapha, K.A.
Abidin, N.S.Z.
Lashin, A.
Yelwa, N.A.
Alqubalee, A.M.
spellingShingle Hakimi, M.H.
Gharib, A.F.
Alqudah, M.
Ahmed, A.
Hatem, B.A.
Mustapha, K.A.
Abidin, N.S.Z.
Lashin, A.
Yelwa, N.A.
Alqubalee, A.M.
Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
author_facet Hakimi, M.H.
Gharib, A.F.
Alqudah, M.
Ahmed, A.
Hatem, B.A.
Mustapha, K.A.
Abidin, N.S.Z.
Lashin, A.
Yelwa, N.A.
Alqubalee, A.M.
author_sort Hakimi, M.H.
title Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
title_short Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
title_full Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
title_fullStr Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
title_full_unstemmed Geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern Jordan: Insights into Type II-S source rock
title_sort geochemistry and organofacies characteristics of organic-rich chalky marl deposits, northern jordan: insights into type ii-s source rock
publisher Elsevier Ltd
publishDate 2022
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85121975181&doi=10.1016%2fj.jseaes.2021.105040&partnerID=40&md5=94b742dfe6a2e9aff5992f93fe2a8cf0
http://eprints.utp.edu.my/28630/
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