Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption

A novel aromatic polyamine covalent triazine-based polymer, CPDA was obtained by the polymerization of amino group (1,4-phenylenediamine) and cyanuric chloride. CPDA was characterized with Fourier Transform Infra-red spectroscopy (FTIR) and the thermal behaviour was studied with thermal gravimetric...

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Main Authors: Lee, S.-P., Mellon, N., Shariff, A.M., Leveque, J.-M.
Format: Article
Published: Institute of Physics Publishing 2017
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028638158&doi=10.1088%2f1757-899X%2f226%2f1%2f012173&partnerID=40&md5=c60b7b60bde1cb9721230f791c8ae08d
http://eprints.utp.edu.my/20031/
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spelling my.utp.eprints.200312018-04-22T14:38:13Z Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption Lee, S.-P. Mellon, N. Shariff, A.M. Leveque, J.-M. A novel aromatic polyamine covalent triazine-based polymer, CPDA was obtained by the polymerization of amino group (1,4-phenylenediamine) and cyanuric chloride. CPDA was characterized with Fourier Transform Infra-red spectroscopy (FTIR) and the thermal behaviour was studied with thermal gravimetric analysis (TGA) and derivative thermal analysis (DTA). A comparison study for CO2 adsorption capacity on covalent organic polymer 1 (COP-1) and CPDA was performed. By introducing the aromatic ring into the nitrogen fertile triazine based system, the thermal stability of the network is enhanced. Polymer structure containing secondary amine functionality was observed in this study. Besides, the suggested chemical pathway is another approach to synthesis of covalent organic materials using economic monomers and absence of expensive catalyst. © Published under licence by IOP Publishing Ltd. Institute of Physics Publishing 2017 Article PeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028638158&doi=10.1088%2f1757-899X%2f226%2f1%2f012173&partnerID=40&md5=c60b7b60bde1cb9721230f791c8ae08d Lee, S.-P. and Mellon, N. and Shariff, A.M. and Leveque, J.-M. (2017) Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption. IOP Conference Series: Materials Science and Engineering, 226 (1). http://eprints.utp.edu.my/20031/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description A novel aromatic polyamine covalent triazine-based polymer, CPDA was obtained by the polymerization of amino group (1,4-phenylenediamine) and cyanuric chloride. CPDA was characterized with Fourier Transform Infra-red spectroscopy (FTIR) and the thermal behaviour was studied with thermal gravimetric analysis (TGA) and derivative thermal analysis (DTA). A comparison study for CO2 adsorption capacity on covalent organic polymer 1 (COP-1) and CPDA was performed. By introducing the aromatic ring into the nitrogen fertile triazine based system, the thermal stability of the network is enhanced. Polymer structure containing secondary amine functionality was observed in this study. Besides, the suggested chemical pathway is another approach to synthesis of covalent organic materials using economic monomers and absence of expensive catalyst. © Published under licence by IOP Publishing Ltd.
format Article
author Lee, S.-P.
Mellon, N.
Shariff, A.M.
Leveque, J.-M.
spellingShingle Lee, S.-P.
Mellon, N.
Shariff, A.M.
Leveque, J.-M.
Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
author_facet Lee, S.-P.
Mellon, N.
Shariff, A.M.
Leveque, J.-M.
author_sort Lee, S.-P.
title Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
title_short Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
title_full Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
title_fullStr Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
title_full_unstemmed Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
title_sort aromatic polyamines covalent triazine polymer as sorbent for co2 adsorption
publisher Institute of Physics Publishing
publishDate 2017
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028638158&doi=10.1088%2f1757-899X%2f226%2f1%2f012173&partnerID=40&md5=c60b7b60bde1cb9721230f791c8ae08d
http://eprints.utp.edu.my/20031/
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