Aromatic Polyamines Covalent Triazine Polymer as Sorbent for CO2 Adsorption
A novel aromatic polyamine covalent triazine-based polymer, CPDA was obtained by the polymerization of amino group (1,4-phenylenediamine) and cyanuric chloride. CPDA was characterized with Fourier Transform Infra-red spectroscopy (FTIR) and the thermal behaviour was studied with thermal gravimetric...
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| Main Authors: | , , , |
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| Format: | Article |
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Institute of Physics Publishing
2017
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028638158&doi=10.1088%2f1757-899X%2f226%2f1%2f012173&partnerID=40&md5=c60b7b60bde1cb9721230f791c8ae08d http://eprints.utp.edu.my/20031/ |
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| Summary: | A novel aromatic polyamine covalent triazine-based polymer, CPDA was obtained by the polymerization of amino group (1,4-phenylenediamine) and cyanuric chloride. CPDA was characterized with Fourier Transform Infra-red spectroscopy (FTIR) and the thermal behaviour was studied with thermal gravimetric analysis (TGA) and derivative thermal analysis (DTA). A comparison study for CO2 adsorption capacity on covalent organic polymer 1 (COP-1) and CPDA was performed. By introducing the aromatic ring into the nitrogen fertile triazine based system, the thermal stability of the network is enhanced. Polymer structure containing secondary amine functionality was observed in this study. Besides, the suggested chemical pathway is another approach to synthesis of covalent organic materials using economic monomers and absence of expensive catalyst. © Published under licence by IOP Publishing Ltd. |
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