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Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials

Low-cost Mn2+-doped willemite (α-Zn2SiO4:Mn2+) based glass–ceramics were synthesized by conventional melt–quenching technique using waste soda lime silica (SLS) glasses, zinc oxide (ZnO) and Manganese oxide (MnO) as precursors. The effect of different MnO percentage doping on physical, structural, o...

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Main Authors: Mohd Zaid, Mohd Hafiz, Matori, Khamirul Amin, Ab Aziz, Sidek, Mohamed Kamari, Halimah, Ismail, Ismayadi, Samsudin, Nur Farhana, Abdul Rashid, Siti Syuhaida
Format: Article
Language:English
Published: Springer 2017
Online Access:http://psasir.upm.edu.my/id/eprint/61722/1/Enhanced%20luminescence%20properties%20of%20low-cost%20.pdf
http://psasir.upm.edu.my/id/eprint/61722/
https://link.springer.com/article/10.1007/s10854-017-7045-9
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spelling my.upm.eprints.617222019-01-10T07:05:59Z http://psasir.upm.edu.my/id/eprint/61722/ Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Ab Aziz, Sidek Mohamed Kamari, Halimah Ismail, Ismayadi Samsudin, Nur Farhana Abdul Rashid, Siti Syuhaida Low-cost Mn2+-doped willemite (α-Zn2SiO4:Mn2+) based glass–ceramics were synthesized by conventional melt–quenching technique using waste soda lime silica (SLS) glasses, zinc oxide (ZnO) and Manganese oxide (MnO) as precursors. The effect of different MnO percentage doping on physical, structural, optical and luminescent performance α-Zn2SiO4:Mn2+ based glass–ceramics were comprehensively studies in this work. The presence of α-Zn2SiO4:Mn2+ crystal phase and microstructure was confirmed by X-ray diffraction and field emission scanning electron microscopy spectroscopy. From the Scherrer’s formula, α-Zn2SiO4:Mn2+ have an average crystallite size of 30–40 nm, respectively. Fourier transform infrared reflection spectroscopy displays the structural growth of α-Zn2SiO4:Mn2+ crystal. The green emission centered at about 527 nm from the α-Zn2SiO4:Mn2+ crystal exhibit a resulted from 4T1–6A1 energy transition of Mn2+ ions. Intense emissions of Mn2+ ions at 260 nm excitation were occurs may be caused by the increase of Mn2+ ions into α-Zn2SiO4 crystal structure with lower phonon. Based on the results achieved, this low-cost α-Zn2SiO4:Mn2+ based glass–ceramic exhibit a huge potential to act as a green phosphor in opto-electronic devices. Springer 2017-08 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/61722/1/Enhanced%20luminescence%20properties%20of%20low-cost%20.pdf Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Ab Aziz, Sidek and Mohamed Kamari, Halimah and Ismail, Ismayadi and Samsudin, Nur Farhana and Abdul Rashid, Siti Syuhaida (2017) Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials. Journal of Materials Science: Materials in Electronics, 28 (16). 12282 - 12289. ISSN 0957-4522; ESSN: 1573-482X https://link.springer.com/article/10.1007/s10854-017-7045-9 10.1007/s10854-017-7045-9
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Low-cost Mn2+-doped willemite (α-Zn2SiO4:Mn2+) based glass–ceramics were synthesized by conventional melt–quenching technique using waste soda lime silica (SLS) glasses, zinc oxide (ZnO) and Manganese oxide (MnO) as precursors. The effect of different MnO percentage doping on physical, structural, optical and luminescent performance α-Zn2SiO4:Mn2+ based glass–ceramics were comprehensively studies in this work. The presence of α-Zn2SiO4:Mn2+ crystal phase and microstructure was confirmed by X-ray diffraction and field emission scanning electron microscopy spectroscopy. From the Scherrer’s formula, α-Zn2SiO4:Mn2+ have an average crystallite size of 30–40 nm, respectively. Fourier transform infrared reflection spectroscopy displays the structural growth of α-Zn2SiO4:Mn2+ crystal. The green emission centered at about 527 nm from the α-Zn2SiO4:Mn2+ crystal exhibit a resulted from 4T1–6A1 energy transition of Mn2+ ions. Intense emissions of Mn2+ ions at 260 nm excitation were occurs may be caused by the increase of Mn2+ ions into α-Zn2SiO4 crystal structure with lower phonon. Based on the results achieved, this low-cost α-Zn2SiO4:Mn2+ based glass–ceramic exhibit a huge potential to act as a green phosphor in opto-electronic devices.
format Article
author Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Ab Aziz, Sidek
Mohamed Kamari, Halimah
Ismail, Ismayadi
Samsudin, Nur Farhana
Abdul Rashid, Siti Syuhaida
spellingShingle Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Ab Aziz, Sidek
Mohamed Kamari, Halimah
Ismail, Ismayadi
Samsudin, Nur Farhana
Abdul Rashid, Siti Syuhaida
Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
author_facet Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Ab Aziz, Sidek
Mohamed Kamari, Halimah
Ismail, Ismayadi
Samsudin, Nur Farhana
Abdul Rashid, Siti Syuhaida
author_sort Mohd Zaid, Mohd Hafiz
title Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
title_short Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
title_full Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
title_fullStr Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
title_full_unstemmed Enhanced luminescence properties of low-cost Mn2+ doped willemite based glass–ceramics as potential green phosphor materials
title_sort enhanced luminescence properties of low-cost mn2+ doped willemite based glass–ceramics as potential green phosphor materials
publisher Springer
publishDate 2017
url http://psasir.upm.edu.my/id/eprint/61722/1/Enhanced%20luminescence%20properties%20of%20low-cost%20.pdf
http://psasir.upm.edu.my/id/eprint/61722/
https://link.springer.com/article/10.1007/s10854-017-7045-9
_version_ 1643837581719240704
score 13.211869

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