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Dimethylsulphoxide Complexes of Vanadium(III)

Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead...

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Main Authors: Sirat, Kamaliah, W.Smith, Peter
Format: Article
Language:English
English
Published: 1992
Online Access:http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf
http://psasir.upm.edu.my/id/eprint/2939/
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spelling my.upm.eprints.29392013-05-27T07:04:35Z http://psasir.upm.edu.my/id/eprint/2939/ Dimethylsulphoxide Complexes of Vanadium(III) Sirat, Kamaliah W.Smith, Peter Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively 1992 Article NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf Sirat, Kamaliah and W.Smith, Peter (1992) Dimethylsulphoxide Complexes of Vanadium(III). Pertanika, 15 (2). pp. 137-142. English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively
format Article
author Sirat, Kamaliah
W.Smith, Peter
spellingShingle Sirat, Kamaliah
W.Smith, Peter
Dimethylsulphoxide Complexes of Vanadium(III)
author_facet Sirat, Kamaliah
W.Smith, Peter
author_sort Sirat, Kamaliah
title Dimethylsulphoxide Complexes of Vanadium(III)
title_short Dimethylsulphoxide Complexes of Vanadium(III)
title_full Dimethylsulphoxide Complexes of Vanadium(III)
title_fullStr Dimethylsulphoxide Complexes of Vanadium(III)
title_full_unstemmed Dimethylsulphoxide Complexes of Vanadium(III)
title_sort dimethylsulphoxide complexes of vanadium(iii)
publishDate 1992
url http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf
http://psasir.upm.edu.my/id/eprint/2939/
_version_ 1643822465954086912
score 13.211869

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