Dimethylsulphoxide Complexes of Vanadium(III)
Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English English |
| Published: |
1992
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| Online Access: | http://psasir.upm.edu.my/id/eprint/2939/1/Dimethylsulphoxide_Complexes_of_Vanadium%28III%29.pdf http://psasir.upm.edu.my/id/eprint/2939/ |
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| Summary: | Dimethylsulphaxide(DMSO) compkxsalts of vanadium(IIl) with theemfrincalformulae VCI,. 6DMSOand VBr,. 6DMSO
were synthesized and investigated. The observed infra-red band positions of the v(S.O) stretch indicate that the ligand is coordinated to ·vanadium ion via oxygen. Far-infra-l-ed spectra lead to the conclusion that no-1U of the halide ions are eoen·dinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly, the chlarideand bromide salts areformulated as [V(DMSO)jCI, and [V[DMSOljBrp respectively |
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