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Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.

The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.

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Main Authors: Lajis, Nordin Hj., Khan, Mohammad Niyaz
Format: Article
Published: Elsevier 1992
Online Access:http://psasir.upm.edu.my/id/eprint/114121/
https://linkinghub.elsevier.com/retrieve/pii/S0040402001882065
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id my.upm.eprints.114121
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spelling my.upm.eprints.1141212024-12-03T04:03:03Z http://psasir.upm.edu.my/id/eprint/114121/ Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. Lajis, Nordin Hj. Khan, Mohammad Niyaz The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction. Elsevier 1992-05 Article PeerReviewed Lajis, Nordin Hj. and Khan, Mohammad Niyaz (1992) Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides. Tetrahedron, 48 (6). pp. 1109-1114. ISSN 0040-4020; eISSN: 0040-4020 https://linkinghub.elsevier.com/retrieve/pii/S0040402001882065 10.1016/s0040-4020(01)88206-5
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.
format Article
author Lajis, Nordin Hj.
Khan, Mohammad Niyaz
spellingShingle Lajis, Nordin Hj.
Khan, Mohammad Niyaz
Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
author_facet Lajis, Nordin Hj.
Khan, Mohammad Niyaz
author_sort Lajis, Nordin Hj.
title Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
title_short Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
title_full Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
title_fullStr Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
title_full_unstemmed Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
title_sort solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
publisher Elsevier
publishDate 1992
url http://psasir.upm.edu.my/id/eprint/114121/
https://linkinghub.elsevier.com/retrieve/pii/S0040402001882065
_version_ 1817844704003227648
score 13.223943

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