Solvolytic stereoselective coupling reaction of p-methoxyphenylmagnesium bromide with substituted allylic chlorides.
The α- and γ-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to involve the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects of both on the regio- and stereo-selectivity of the reaction.
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| Main Authors: | , |
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| Format: | Article |
| Published: |
Elsevier
1992
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| Online Access: | http://psasir.upm.edu.my/id/eprint/114121/ https://linkinghub.elsevier.com/retrieve/pii/S0040402001882065 |
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