{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra...
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International Union of Crystallography
2011
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Online Access: | http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf http://ir.unimas.my/id/eprint/7354/ http://journals.iucr.org/e/issues/2011/07/00/hb5915/hb5915.pdf |
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my.unimas.ir.73542015-05-25T07:05:44Z http://ir.unimas.my/id/eprint/7354/ {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) Fasihuddin B, Ahmad Fraser, White MA, Affan Edward R. T., Tiekink Norrihan B, Sam QD Chemistry The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds, and weak C—H interactions consolidate the packing. International Union of Crystallography 2011 E-Article PeerReviewed text en http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf Fasihuddin B, Ahmad and Fraser, White and MA, Affan and Edward R. T., Tiekink and Norrihan B, Sam (2011) {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 67 (7). m965-m965. ISSN 1600-5368 http://journals.iucr.org/e/issues/2011/07/00/hb5915/hb5915.pdf 10.1107/S1600536811023 |
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QD Chemistry Fasihuddin B, Ahmad Fraser, White MA, Affan Edward R. T., Tiekink Norrihan B, Sam {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
description |
The SnIV atom in the title compound, [Sn(CH3)2-
(C17H14N2O3)], is five-coordinated within a C2N2O donor set
provided by the N,N,O-tridentate ligand and two methyl
groups. The resultant coordination geometry is intermediate
between trigonal-bipyramidal and square-pyramidal. In the
crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds,
and weak C—H interactions consolidate the packing. |
format |
E-Article |
author |
Fasihuddin B, Ahmad Fraser, White MA, Affan Edward R. T., Tiekink Norrihan B, Sam |
author_facet |
Fasihuddin B, Ahmad Fraser, White MA, Affan Edward R. T., Tiekink Norrihan B, Sam |
author_sort |
Fasihuddin B, Ahmad |
title |
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
title_short |
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
title_full |
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
title_fullStr |
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
title_full_unstemmed |
{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV) |
title_sort |
{4-hydroxy-n0-[(2e,3z)-4-oxido-4-
phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(iv) |
publisher |
International Union of Crystallography |
publishDate |
2011 |
url |
http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf http://ir.unimas.my/id/eprint/7354/ http://journals.iucr.org/e/issues/2011/07/00/hb5915/hb5915.pdf |
_version_ |
1644510264312201216 |
score |
13.211869 |