{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV)
The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra...
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| Main Authors: | , , , , |
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| Format: | E-Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://ir.unimas.my/id/eprint/7354/1/%7B4-Hydroxy-N0-%5B%282E%2C3Z%29-4-oxido-4-%20phenylbut-3-en-2-ylidene%5Dbenzohydrazidato%7Ddimethyltin%28IV%29.pdf http://ir.unimas.my/id/eprint/7354/ http://journals.iucr.org/e/issues/2011/07/00/hb5915/hb5915.pdf |
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| Summary: | The SnIV atom in the title compound, [Sn(CH3)2-
(C17H14N2O3)], is five-coordinated within a C2N2O donor set
provided by the N,N,O-tridentate ligand and two methyl
groups. The resultant coordination geometry is intermediate
between trigonal-bipyramidal and square-pyramidal. In the
crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds,
and weak C—H interactions consolidate the packing. |
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