Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand
Six new Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes (2-7) of o-vanillin benzoylhydrazone ligand (1) have been synthesized and characterized. The ligand (1) and its 3dmetal complexes (2-7) were characterized by elemental analysis, molar conductivity, UVVisible, FT-IR and 1H NMR spectr...
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2012
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my.unimas.ir.334302023-10-30T04:17:04Z http://ir.unimas.my/id/eprint/33430/ Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand Husna Sarfina, Husain GE Environmental Sciences Six new Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes (2-7) of o-vanillin benzoylhydrazone ligand (1) have been synthesized and characterized. The ligand (1) and its 3dmetal complexes (2-7) were characterized by elemental analysis, molar conductivity, UVVisible, FT-IR and 1H NMR spectroscopic studies. The spectroscopic data of the complexes (2- 7) suggested that the ligand (1) is acted as a dinegative tridentate chelating system and is coordinated to central metal(II) atom through phenoxide-O, atomethine-N and carboxylate-O atoms. Four coordinated molecular structure has been proposed for the synthesized 3d-transition metal complexes. The ligand (1) and its metal complexes (2-7) have also been tested for their cytotoxicity and found to be less active against Artemia salina. Universiti Malaysia Sarawak, (UNIMAS) 2012 Final Year Project Report NonPeerReviewed text en http://ir.unimas.my/id/eprint/33430/3/Husna%20Sarfina.pdf Husna Sarfina, Husain (2012) Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand. [Final Year Project Report] (Unpublished) |
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GE Environmental Sciences Husna Sarfina, Husain Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
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Six new Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes (2-7) of o-vanillin benzoylhydrazone ligand (1) have been synthesized and characterized. The ligand (1) and its 3dmetal complexes (2-7) were characterized by elemental analysis, molar conductivity, UVVisible, FT-IR and 1H NMR spectroscopic studies. The spectroscopic data of the complexes (2- 7) suggested that the ligand (1) is acted as a dinegative tridentate chelating system and is coordinated to central metal(II) atom through phenoxide-O, atomethine-N and carboxylate-O atoms. Four coordinated molecular structure has been proposed for the synthesized 3d-transition metal complexes. The ligand (1) and its metal complexes (2-7) have also been tested for their cytotoxicity and found to be less active against Artemia salina. |
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Final Year Project Report |
author |
Husna Sarfina, Husain |
author_facet |
Husna Sarfina, Husain |
author_sort |
Husna Sarfina, Husain |
title |
Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
title_short |
Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
title_full |
Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
title_fullStr |
Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
title_full_unstemmed |
Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand |
title_sort |
synthesis, spectral characterization and cytotoxic activity of 3d-transition metal complexes with o-vanillin benzoylhydrazone ligand |
publisher |
Universiti Malaysia Sarawak, (UNIMAS) |
publishDate |
2012 |
url |
http://ir.unimas.my/id/eprint/33430/3/Husna%20Sarfina.pdf http://ir.unimas.my/id/eprint/33430/ |
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1781710395752316928 |
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13.211869 |