Synthesis, spectral characterization and cytotoxic activity of 3D-Transition metal complexes with O-Vanillin Benzoylhydrazone Ligand
Six new Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes (2-7) of o-vanillin benzoylhydrazone ligand (1) have been synthesized and characterized. The ligand (1) and its 3dmetal complexes (2-7) were characterized by elemental analysis, molar conductivity, UVVisible, FT-IR and 1H NMR spectr...
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| 第一著者: | |
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| フォーマット: | Final Year Project Report |
| 言語: | English |
| 出版事項: |
Universiti Malaysia Sarawak, (UNIMAS)
2012
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| オンライン･アクセス: | http://ir.unimas.my/id/eprint/33430/3/Husna%20Sarfina.pdf http://ir.unimas.my/id/eprint/33430/ |
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| 要約: | Six new Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes (2-7) of o-vanillin benzoylhydrazone ligand (1) have been synthesized and characterized. The ligand (1) and its 3dmetal complexes (2-7) were characterized by elemental analysis, molar conductivity, UVVisible, FT-IR and 1H NMR spectroscopic studies. The spectroscopic data of the complexes (2- 7) suggested that the ligand (1) is acted as a dinegative tridentate chelating system and is coordinated to central metal(II) atom through phenoxide-O, atomethine-N and carboxylate-O atoms. Four coordinated molecular structure has been proposed for the synthesized 3d-transition metal complexes. The ligand (1) and its metal complexes (2-7) have also been tested for their cytotoxicity and found to be less active against Artemia salina. |
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