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Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms

Each of the bidentate and tridentate Schiffbase ligands containing a donor set ofNN- and ONN- atoms were prepared by condensation reaction of 2- ridinecarbaxaldehyde with phenylhydrazine and salicylaldehyde with 2-dimethylaminoethylamine. Five organotin(lV) complexes (3-7) of 2-pyridinecarbaxaldehy...

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Main Author: Anne Eliza, Anak Dolim
Format: Final Year Project Report
Language:English
Published: Universiti Malaysia Sarawak (UNIMAS) 2010
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://ir.unimas.my/id/eprint/25557/1/Anne%20Eliza%20Ak%20Dolim%20ft.pdf
http://ir.unimas.my/id/eprint/25557/
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spelling my.unimas.ir.255572023-02-27T09:34:39Z http://ir.unimas.my/id/eprint/25557/ Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms Anne Eliza, Anak Dolim Q Science (General) QD Chemistry Each of the bidentate and tridentate Schiffbase ligands containing a donor set ofNN- and ONN- atoms were prepared by condensation reaction of 2- ridinecarbaxaldehyde with phenylhydrazine and salicylaldehyde with 2-dimethylaminoethylamine. Five organotin(lV) complexes (3-7) of 2-pyridinecarbaxaldehyde phenyl hydrazone ligand (I) with R"SnCl,." (n = 1,2) have been synthesized in absolute hexane in 1:1 mole ration (/igand:metal) under nitrogen atmosphere. Two organotin(IV) complexes (8-9) were synthesized by the similar reaction with 2-hydroxybenzylidene-2-dimethylaminoethylamine ligand (2). Schiff base ligands (1-2) and their organotin(lV) complexes (3-9) have been characterized by UV-visible, molar conductance, FTlR and IH NMR spectral analyses. A six-coordinated molecular structure has been proposed for the synthesized organotin(IV) complexes (3-9) for both ligands (1-2). Universiti Malaysia Sarawak (UNIMAS) 2010 Final Year Project Report PeerReviewed text en http://ir.unimas.my/id/eprint/25557/1/Anne%20Eliza%20Ak%20Dolim%20ft.pdf Anne Eliza, Anak Dolim (2010) Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms. [Final Year Project Report] (Unpublished)
institution Universiti Malaysia Sarawak
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
url_provider http://ir.unimas.my/
language English
topic Q Science (General)
QD Chemistry
spellingShingle Q Science (General)
QD Chemistry
Anne Eliza, Anak Dolim
Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
description Each of the bidentate and tridentate Schiffbase ligands containing a donor set ofNN- and ONN- atoms were prepared by condensation reaction of 2- ridinecarbaxaldehyde with phenylhydrazine and salicylaldehyde with 2-dimethylaminoethylamine. Five organotin(lV) complexes (3-7) of 2-pyridinecarbaxaldehyde phenyl hydrazone ligand (I) with R"SnCl,." (n = 1,2) have been synthesized in absolute hexane in 1:1 mole ration (/igand:metal) under nitrogen atmosphere. Two organotin(IV) complexes (8-9) were synthesized by the similar reaction with 2-hydroxybenzylidene-2-dimethylaminoethylamine ligand (2). Schiff base ligands (1-2) and their organotin(lV) complexes (3-9) have been characterized by UV-visible, molar conductance, FTlR and IH NMR spectral analyses. A six-coordinated molecular structure has been proposed for the synthesized organotin(IV) complexes (3-9) for both ligands (1-2).
format Final Year Project Report
author Anne Eliza, Anak Dolim
author_facet Anne Eliza, Anak Dolim
author_sort Anne Eliza, Anak Dolim
title Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
title_short Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
title_full Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
title_fullStr Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
title_full_unstemmed Synthesis and characterization of organotin(IV) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
title_sort synthesis and characterization of organotin(iv) complexes of bidentate and tridentate schiff base ligands containing nn and onn-donor atoms
publisher Universiti Malaysia Sarawak (UNIMAS)
publishDate 2010
url http://ir.unimas.my/id/eprint/25557/1/Anne%20Eliza%20Ak%20Dolim%20ft.pdf
http://ir.unimas.my/id/eprint/25557/
_version_ 1759693308125249536
score 13.211869

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