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Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the sma...

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Main Authors: Vafaee, M., Amini, M.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/12560/
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spelling my.um.eprints.125602019-01-30T08:32:23Z http://eprints.um.edu.my/12560/ Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV) Vafaee, M. Amini, M.M. Ng, S.W. QD Chemistry The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the smaller C-Sn-C angle interacts weakly with the SnIV atom of the molecule with the wider C-Sn-C angle at an Sn...Cl distance of 3.595 (1) A. Weak intermolecular C-H...O and C-H...Cl hydrogen bonding is present in the crystal structure. International Union of Crystallography 2010 Article PeerReviewed Vafaee, M. and Amini, M.M. and Ng, S.W. (2010) Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (8). M965-U958. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Vafaee, M.
Amini, M.M.
Ng, S.W.
Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
description The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the smaller C-Sn-C angle interacts weakly with the SnIV atom of the molecule with the wider C-Sn-C angle at an Sn...Cl distance of 3.595 (1) A. Weak intermolecular C-H...O and C-H...Cl hydrogen bonding is present in the crystal structure.
format Article
author Vafaee, M.
Amini, M.M.
Ng, S.W.
author_facet Vafaee, M.
Amini, M.M.
Ng, S.W.
author_sort Vafaee, M.
title Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
title_short Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
title_full Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
title_fullStr Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
title_full_unstemmed Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
title_sort chloridomethyl(2-methylquinolin-8-olato-kappa 2 n,o)phenyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12560/
_version_ 1643689325240516608
score 13.211869

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