Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the sma...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12560/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the smaller C-Sn-C angle interacts weakly with the SnIV atom of the molecule with the wider C-Sn-C angle at an Sn...Cl distance of 3.595 (1) A. Weak intermolecular C-H...O and C-H...Cl hydrogen bonding is present in the crystal structure. |
|---|