Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the sma...
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| Main Authors: | , , |
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| 格式: | Article |
| 出版: |
International Union of Crystallography
2010
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| 在線閱讀: | http://eprints.um.edu.my/12560/ |
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| 總結: | The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the smaller C-Sn-C angle interacts weakly with the SnIV atom of the molecule with the wider C-Sn-C angle at an Sn...Cl distance of 3.595 (1) A. Weak intermolecular C-H...O and C-H...Cl hydrogen bonding is present in the crystal structure. |
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