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Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n

A novel nano-cauliflower-shaped lead(II) metal–organic coordination polymer, [Pb(μ-2-pinh)N3 H2O]n (1), was synthesized using an ultrasonic method. The nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction, IR spectroscopy, elemental analysis, and thermal an...

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Main Authors: Mirtamizdoust, Babak, Bieńko, Dariusz C., Hanifehpour, Younes, Tiekink, Edward R. T. *, Yilmaz, Veysel T., Talemi, Pejman, Joo, Sang Woo
Format: Article
Language:English
Published: Springer Verlag (Germany) 2016
Subjects:
QD Chemistry
Online Access:http://eprints.sunway.edu.my/650/1/Inorg%20Organomet%20Polym%20%282016%29%2026_819%E2%80%93828.pdf
http://eprints.sunway.edu.my/650/
http://dx.doi.org/10.1007/s10904-016-0385-8
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spelling my.sunway.eprints.6502020-10-07T10:02:02Z http://eprints.sunway.edu.my/650/ Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n Mirtamizdoust, Babak Bieńko, Dariusz C. Hanifehpour, Younes Tiekink, Edward R. T. * Yilmaz, Veysel T. Talemi, Pejman Joo, Sang Woo QD Chemistry A novel nano-cauliflower-shaped lead(II) metal–organic coordination polymer, [Pb(μ-2-pinh)N3 H2O]n (1), was synthesized using an ultrasonic method. The nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction, IR spectroscopy, elemental analysis, and thermal analysis. The compound was structurally characterized by single-crystal X-ray diffraction. The coordination compound takes the form of a zig-zag one-dimensional polymer in solid state. The coordination number of the lead(II) ions is six (PbN4O2) with three nitrogen atoms and one oxygen atom from two linker organic ligands, as well as one oxygen from coordinated water and one nitrogen atom from terminal coordinated azide anion. It has a stereo-chemically active lone electron pair, and the coordination sphere is hemidirected. The zig-zag 1D chains interact with neighbouring chains through weak interactions, creating a 3D supramolecular metal–organic framework. Lead oxide nanoparticles were obtained by thermolysis of the new nano coordination compound at 180 °C with oleic acid as a surfactant. The morphology and size were further studied using SEM. Natural bond orbital analyses demonstrate the electronic properties of the lead centre and other atoms. Springer Verlag (Germany) 2016 Article NonPeerReviewed text en http://eprints.sunway.edu.my/650/1/Inorg%20Organomet%20Polym%20%282016%29%2026_819%E2%80%93828.pdf Mirtamizdoust, Babak and Bieńko, Dariusz C. and Hanifehpour, Younes and Tiekink, Edward R. T. * and Yilmaz, Veysel T. and Talemi, Pejman and Joo, Sang Woo (2016) Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n. Journal of Inorganic and Organometallic Polymers and Materials, 26 (4). pp. 819-828. ISSN 1574-1443 http://dx.doi.org/10.1007/s10904-016-0385-8 doi:10.1007/s10904-016-0385-8
institution Sunway University
building Sunway Campus Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Sunway University
content_source Sunway Institutional Repository
url_provider http://eprints.sunway.edu.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Mirtamizdoust, Babak
Bieńko, Dariusz C.
Hanifehpour, Younes
Tiekink, Edward R. T. *
Yilmaz, Veysel T.
Talemi, Pejman
Joo, Sang Woo
Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
description A novel nano-cauliflower-shaped lead(II) metal–organic coordination polymer, [Pb(μ-2-pinh)N3 H2O]n (1), was synthesized using an ultrasonic method. The nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction, IR spectroscopy, elemental analysis, and thermal analysis. The compound was structurally characterized by single-crystal X-ray diffraction. The coordination compound takes the form of a zig-zag one-dimensional polymer in solid state. The coordination number of the lead(II) ions is six (PbN4O2) with three nitrogen atoms and one oxygen atom from two linker organic ligands, as well as one oxygen from coordinated water and one nitrogen atom from terminal coordinated azide anion. It has a stereo-chemically active lone electron pair, and the coordination sphere is hemidirected. The zig-zag 1D chains interact with neighbouring chains through weak interactions, creating a 3D supramolecular metal–organic framework. Lead oxide nanoparticles were obtained by thermolysis of the new nano coordination compound at 180 °C with oleic acid as a surfactant. The morphology and size were further studied using SEM. Natural bond orbital analyses demonstrate the electronic properties of the lead centre and other atoms.
format Article
author Mirtamizdoust, Babak
Bieńko, Dariusz C.
Hanifehpour, Younes
Tiekink, Edward R. T. *
Yilmaz, Veysel T.
Talemi, Pejman
Joo, Sang Woo
author_facet Mirtamizdoust, Babak
Bieńko, Dariusz C.
Hanifehpour, Younes
Tiekink, Edward R. T. *
Yilmaz, Veysel T.
Talemi, Pejman
Joo, Sang Woo
author_sort Mirtamizdoust, Babak
title Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
title_short Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
title_full Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
title_fullStr Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
title_full_unstemmed Preparation of a Novel Nano-scale Lead (II) Zig-Zag Metal–Organic Coordination Polymer with Ultrasonic Assistance: Synthesis, Crystal Structure, Thermal Properties, and NBO Analysis of [Pb(μ-2-pinh)N3 H2O]n
title_sort preparation of a novel nano-scale lead (ii) zig-zag metal–organic coordination polymer with ultrasonic assistance: synthesis, crystal structure, thermal properties, and nbo analysis of [pb(μ-2-pinh)n3 h2o]n
publisher Springer Verlag (Germany)
publishDate 2016
url http://eprints.sunway.edu.my/650/1/Inorg%20Organomet%20Polym%20%282016%29%2026_819%E2%80%93828.pdf
http://eprints.sunway.edu.my/650/
http://dx.doi.org/10.1007/s10904-016-0385-8
_version_ 1680323390344265728
score 13.211869

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