Properties and reactivity of μ‑nitrido‑bridged dimetal porphyrinoid complexes: how does ruthenium compare to iron?

Methane hydroxylation by metal-oxo oxidants is one of the Holy Grails in biomimetic and biotechnological chemistry. The only enzymes known to perform this reaction in Nature are iron-containing soluble methane monooxygenase and copper-containing particulate methane monooxygenase. Furthermore, few bi...

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Bibliographic Details

Main Authors:	Muhammad Qadri Effendy Mubarak, Alexander B. Sorokin, Sam P. de Visser
Format:	Article
Language:	en_US
Published:	Springer 2024
Subjects:	Biomimetic models,Methane oxidation,μ-Nitrido complexes,High-valent oxo species, Phthalocyanine, Porphyrin
Online Access:	http://dx.doi.org/10.1007/s00775-019-01725-7
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