Properties and reactivity of μ‑nitrido‑bridged dimetal porphyrinoid complexes: how does ruthenium compare to iron?
Methane hydroxylation by metal-oxo oxidants is one of the Holy Grails in biomimetic and biotechnological chemistry. The only enzymes known to perform this reaction in Nature are iron-containing soluble methane monooxygenase and copper-containing particulate methane monooxygenase. Furthermore, few bi...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | en_US |
| Published: |
Springer
2024
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1007/s00775-019-01725-7 |
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