Snap frozen! Capturing two metastable polymorphs in a tetramorphic one-dimensional coordination polymer constructed from cadmium, dithiophosphate, and 4-pyridinealdazine
Four polymorphs are described for the one-dimensional coordination polymer {Cd[S2P(OMe)2]2(4-pyridine-aldazine)}n (1) which features a trans-N2S4 distorted octahedral coordination geometry. Lattice energy calculations show the room temperature form, 1α, is the thermodynamically stable phase, being...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | en |
| Published: |
American Chemical Society
2020
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/1278/1/Tiekink%20Cryst%20Growth%20Des%202020%2020%203272.pdf http://eprints.sunway.edu.my/1278/ http://doi.org/10.1021/acs.cgd.0c00082 |
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