SYNTHESIS AND CHARACTERIZATION OF NEW IONIC LIQUIDS AND ITS POTENTIAL APPLICATIONS FOR BAMBOO BIOMASS

After complete dissolution of bamboo in [Emim]Gly, the separation of bamboo constituents into cellulose rich-material, hemicelluloses and lignin was possible, via selective solvent precipitation method using acetone/water mixture (7 /3 v/v) and ethanol. The individual constituent was confirmed...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: MUHAMMAD, NAWSHAD
التنسيق: أطروحة
اللغة:English
منشور في: 2012
الموضوعات:
الوصول للمادة أونلاين:http://utpedia.utp.edu.my/id/eprint/21307/1/2012%20-CHEMICAL%20-%20SYNTHESIS%20AND%20CHARACTERIZATION%20OF%20NEW%20IONIC%20LIQUIDS%20AND%20ITS%20POTENTIAL%20APPLICATION%20FOR%20BAMBOO%20BIAMASS%20-%20NAWSHAD%20MUHAMMAD.pdf
http://utpedia.utp.edu.my/id/eprint/21307/
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الوصف
الملخص:After complete dissolution of bamboo in [Emim]Gly, the separation of bamboo constituents into cellulose rich-material, hemicelluloses and lignin was possible, via selective solvent precipitation method using acetone/water mixture (7 /3 v/v) and ethanol. The individual constituent was confirmed by FTIR, NMR, HPLC, TGA and CHNS analysis. In terms of efficiency of lignin extraction, the nitrile-based ionic liquids containing Cl perform well compared to [Bmim]Cl. The ionic liquids in the order of increasing extraction efficiency are [Bmim]Cl < [CzCNBim]Cl < [CzCNHEim]Cl < [CzCNAim]Cl < [CzCNBzim]Cl. The increase in heating temperature and time increases lignin extraction, while the increase in particle size and amount of sample loading reduces the extraction efficiency of nitrile-based ionic liquids.