Towards a promising systematic approach to the synthesis of CZTS solar cells

This study aims to enhance the CZTS device's overall efficiency, the key research area has been identified in this study is to explore the effects of a novel, low-cost, and simplified, deposition method to improve the optoelectronic properties of the buffer layer in the fabrication of CZTS thin...

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Main Authors: Najm, A.S., Al-Ghamdi, A., Amin, M.T., Al Ghamdi, A., Moria, H., Holi, A.M., Abed, A.M., AL-Zahrani, A.A., Sopian, K., Bais, B., Sultan, A.J.
Format: Article
Published: Nature Research 2023
Online Access:http://scholars.utp.edu.my/id/eprint/37268/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85171389994&doi=10.1038%2fs41598-023-42641-w&partnerID=40&md5=9adf4c3c03219e46c8ce0803d4355213
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spelling oai:scholars.utp.edu.my:372682023-10-04T08:36:21Z http://scholars.utp.edu.my/id/eprint/37268/ Towards a promising systematic approach to the synthesis of CZTS solar cells Najm, A.S. Al-Ghamdi, A. Amin, M.T. Al Ghamdi, A. Moria, H. Holi, A.M. Abed, A.M. AL-Zahrani, A.A. Sopian, K. Bais, B. Sultan, A.J. This study aims to enhance the CZTS device's overall efficiency, the key research area has been identified in this study is to explore the effects of a novel, low-cost, and simplified, deposition method to improve the optoelectronic properties of the buffer layer in the fabrication of CZTS thin film solar cells. Herein, an effective way of addressing this challenge is through adjusting the absorbers' structure by the concept of doping, sensitized CdS thin film by the bi-functional linker, and an environmentally friendly catalytic green agent. The Linker Assisted and Chemical Bath Deposition (LA-CBD) method was introduced as an innovative and effective hybrid sensitization approach. In the one-step synthesis process, Salvia dye, Ag, and 3-Mercaptopropionic acid (MPA) were used. Generally, the results for all samples displayed varying bandgap as achieved between (2.21�2.46) eV, hexagonal structure with considerably decreased strain level, broader grain size, and dramatically enhanced crystalline property. Hence, the rudimentary CdS/CZTS solar cell devices were fabricated for the application of these novel CdS films. Preliminary CZTS thin film solar cell fabrication results in the highest conversion efficiency of 0.266 obtained CdS + Salvia dye, indicating the potential use of the CdS films as a buffer layer for CZTS photovoltaic devices. © 2023, Springer Nature Limited. Nature Research 2023 Article NonPeerReviewed Najm, A.S. and Al-Ghamdi, A. and Amin, M.T. and Al Ghamdi, A. and Moria, H. and Holi, A.M. and Abed, A.M. and AL-Zahrani, A.A. and Sopian, K. and Bais, B. and Sultan, A.J. (2023) Towards a promising systematic approach to the synthesis of CZTS solar cells. Scientific Reports, 13 (1). ISSN 20452322 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85171389994&doi=10.1038%2fs41598-023-42641-w&partnerID=40&md5=9adf4c3c03219e46c8ce0803d4355213 10.1038/s41598-023-42641-w 10.1038/s41598-023-42641-w 10.1038/s41598-023-42641-w
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description This study aims to enhance the CZTS device's overall efficiency, the key research area has been identified in this study is to explore the effects of a novel, low-cost, and simplified, deposition method to improve the optoelectronic properties of the buffer layer in the fabrication of CZTS thin film solar cells. Herein, an effective way of addressing this challenge is through adjusting the absorbers' structure by the concept of doping, sensitized CdS thin film by the bi-functional linker, and an environmentally friendly catalytic green agent. The Linker Assisted and Chemical Bath Deposition (LA-CBD) method was introduced as an innovative and effective hybrid sensitization approach. In the one-step synthesis process, Salvia dye, Ag, and 3-Mercaptopropionic acid (MPA) were used. Generally, the results for all samples displayed varying bandgap as achieved between (2.21�2.46) eV, hexagonal structure with considerably decreased strain level, broader grain size, and dramatically enhanced crystalline property. Hence, the rudimentary CdS/CZTS solar cell devices were fabricated for the application of these novel CdS films. Preliminary CZTS thin film solar cell fabrication results in the highest conversion efficiency of 0.266 obtained CdS + Salvia dye, indicating the potential use of the CdS films as a buffer layer for CZTS photovoltaic devices. © 2023, Springer Nature Limited.
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author Najm, A.S.
Al-Ghamdi, A.
Amin, M.T.
Al Ghamdi, A.
Moria, H.
Holi, A.M.
Abed, A.M.
AL-Zahrani, A.A.
Sopian, K.
Bais, B.
Sultan, A.J.
spellingShingle Najm, A.S.
Al-Ghamdi, A.
Amin, M.T.
Al Ghamdi, A.
Moria, H.
Holi, A.M.
Abed, A.M.
AL-Zahrani, A.A.
Sopian, K.
Bais, B.
Sultan, A.J.
Towards a promising systematic approach to the synthesis of CZTS solar cells
author_facet Najm, A.S.
Al-Ghamdi, A.
Amin, M.T.
Al Ghamdi, A.
Moria, H.
Holi, A.M.
Abed, A.M.
AL-Zahrani, A.A.
Sopian, K.
Bais, B.
Sultan, A.J.
author_sort Najm, A.S.
title Towards a promising systematic approach to the synthesis of CZTS solar cells
title_short Towards a promising systematic approach to the synthesis of CZTS solar cells
title_full Towards a promising systematic approach to the synthesis of CZTS solar cells
title_fullStr Towards a promising systematic approach to the synthesis of CZTS solar cells
title_full_unstemmed Towards a promising systematic approach to the synthesis of CZTS solar cells
title_sort towards a promising systematic approach to the synthesis of czts solar cells
publisher Nature Research
publishDate 2023
url http://scholars.utp.edu.my/id/eprint/37268/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85171389994&doi=10.1038%2fs41598-023-42641-w&partnerID=40&md5=9adf4c3c03219e46c8ce0803d4355213
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