Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes

Flat-sheet asymmetric polysulfone (PSF)/ polyimide (PI) blended membranes were fabricated by a phase-inversion technique. The fabricated membranes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and field emission scanning electron microscopy an...

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Main Authors: Man, Zakaria, Sikander, Rafiq, Saikat, Maitra, Muhammad, Nawshad
Format: Citation Index Journal
Published: 2012
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Online Access:http://eprints.utp.edu.my/8607/1/j_app_polym_sci.pdf
http://eprints.utp.edu.my/8607/
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spelling my.utp.eprints.86072017-01-19T08:22:00Z Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes Man, Zakaria Sikander, Rafiq Saikat, Maitra Muhammad, Nawshad TP Chemical technology Flat-sheet asymmetric polysulfone (PSF)/ polyimide (PI) blended membranes were fabricated by a phase-inversion technique. The fabricated membranes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and field emission scanning electron microscopy analyses. The kinetics of thermal degradation of the membranes were studied from thermogravimetric data following Friedman’s kinetic approach. The thermal degradation process of the membranes followed first-order rate kinetics, and the activation energy of the thermal degradation process increased with increasing PI content of the membrane compositions. VC 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 3755–3763, 2012 Key words: activation energy; blends; degradation; membranes; thermogravimetric analysis (TGA) 2012 Citation Index Journal PeerReviewed application/pdf http://eprints.utp.edu.my/8607/1/j_app_polym_sci.pdf Man, Zakaria and Sikander, Rafiq and Saikat, Maitra and Muhammad, Nawshad (2012) Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes. [Citation Index Journal] http://eprints.utp.edu.my/8607/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Man, Zakaria
Sikander, Rafiq
Saikat, Maitra
Muhammad, Nawshad
Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
description Flat-sheet asymmetric polysulfone (PSF)/ polyimide (PI) blended membranes were fabricated by a phase-inversion technique. The fabricated membranes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and field emission scanning electron microscopy analyses. The kinetics of thermal degradation of the membranes were studied from thermogravimetric data following Friedman’s kinetic approach. The thermal degradation process of the membranes followed first-order rate kinetics, and the activation energy of the thermal degradation process increased with increasing PI content of the membrane compositions. VC 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 3755–3763, 2012 Key words: activation energy; blends; degradation; membranes; thermogravimetric analysis (TGA)
format Citation Index Journal
author Man, Zakaria
Sikander, Rafiq
Saikat, Maitra
Muhammad, Nawshad
author_facet Man, Zakaria
Sikander, Rafiq
Saikat, Maitra
Muhammad, Nawshad
author_sort Man, Zakaria
title Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
title_short Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
title_full Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
title_fullStr Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
title_full_unstemmed Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
title_sort kinetics of thermal degradation of polysulfone/polyimide blended polymeric membranes
publishDate 2012
url http://eprints.utp.edu.my/8607/1/j_app_polym_sci.pdf
http://eprints.utp.edu.my/8607/
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score 13.211869