Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes
Flat-sheet asymmetric polysulfone (PSF)/ polyimide (PI) blended membranes were fabricated by a phase-inversion technique. The fabricated membranes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and field emission scanning electron microscopy an...
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my.utp.eprints.86072017-01-19T08:22:00Z Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes Man, Zakaria Sikander, Rafiq Saikat, Maitra Muhammad, Nawshad TP Chemical technology Flat-sheet asymmetric polysulfone (PSF)/ polyimide (PI) blended membranes were fabricated by a phase-inversion technique. The fabricated membranes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, and field emission scanning electron microscopy analyses. The kinetics of thermal degradation of the membranes were studied from thermogravimetric data following Friedman’s kinetic approach. The thermal degradation process of the membranes followed first-order rate kinetics, and the activation energy of the thermal degradation process increased with increasing PI content of the membrane compositions. VC 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 3755–3763, 2012 Key words: activation energy; blends; degradation; membranes; thermogravimetric analysis (TGA) 2012 Citation Index Journal PeerReviewed application/pdf http://eprints.utp.edu.my/8607/1/j_app_polym_sci.pdf Man, Zakaria and Sikander, Rafiq and Saikat, Maitra and Muhammad, Nawshad (2012) Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes. [Citation Index Journal] http://eprints.utp.edu.my/8607/ |
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TP Chemical technology Man, Zakaria Sikander, Rafiq Saikat, Maitra Muhammad, Nawshad Kinetics of Thermal Degradation of Polysulfone/Polyimide Blended Polymeric Membranes |
description |
Flat-sheet asymmetric polysulfone (PSF)/
polyimide (PI) blended membranes were fabricated by a
phase-inversion technique. The fabricated membranes
were characterized by Fourier transform infrared spectroscopy,
differential scanning calorimetry, and field emission
scanning electron microscopy analyses. The kinetics of
thermal degradation of the membranes were studied from
thermogravimetric data following Friedman’s kinetic
approach. The thermal degradation process of the membranes
followed first-order rate kinetics, and the activation
energy of the thermal degradation process increased with
increasing PI content of the membrane compositions. VC 2011
Wiley Periodicals, Inc. J Appl Polym Sci 123: 3755–3763, 2012
Key words: activation energy; blends; degradation;
membranes; thermogravimetric analysis (TGA) |
format |
Citation Index Journal |
author |
Man, Zakaria Sikander, Rafiq Saikat, Maitra Muhammad, Nawshad |
author_facet |
Man, Zakaria Sikander, Rafiq Saikat, Maitra Muhammad, Nawshad |
author_sort |
Man, Zakaria |
title |
Kinetics of Thermal Degradation of Polysulfone/Polyimide
Blended Polymeric Membranes |
title_short |
Kinetics of Thermal Degradation of Polysulfone/Polyimide
Blended Polymeric Membranes |
title_full |
Kinetics of Thermal Degradation of Polysulfone/Polyimide
Blended Polymeric Membranes |
title_fullStr |
Kinetics of Thermal Degradation of Polysulfone/Polyimide
Blended Polymeric Membranes |
title_full_unstemmed |
Kinetics of Thermal Degradation of Polysulfone/Polyimide
Blended Polymeric Membranes |
title_sort |
kinetics of thermal degradation of polysulfone/polyimide
blended polymeric membranes |
publishDate |
2012 |
url |
http://eprints.utp.edu.my/8607/1/j_app_polym_sci.pdf http://eprints.utp.edu.my/8607/ |
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1738655667224313856 |
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13.211869 |