Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil
In this study, TPA-impregnated SnO2@Co-ZIF catalyst was synthesized to employ for biodiesel production from locally available Mazari palm feedstock. The morphological and structural properties of the synthesized catalyst were studied by different analytical techniques such as Thermal gravimetric ana...
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2022
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my.utp.eprints.334912022-09-07T07:05:07Z Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil Sahar, J. Farooq, M. Ramli, A. Naeem, A. Khattak, N.S. Ghazi, Z.A. In this study, TPA-impregnated SnO2@Co-ZIF catalyst was synthesized to employ for biodiesel production from locally available Mazari palm feedstock. The morphological and structural properties of the synthesized catalyst were studied by different analytical techniques such as Thermal gravimetric analysis (TGA/DTA), X-Ray diffraction analysis (XRD), Scanning electron microscopy (SEM), Energy dispersive X-Ray (EDX) analysis, Fourier transform infrared spectroscopy (FT-IR), Brunauer Emmett Teller (BET) and Temperature Programmed Desorption of ammonia (NH3�TPD) and carbon dioxide (CO2�TPD) to identify suitable catalyst formulation for efficient biodiesel production from Mazari palm oil. The important variables such as molar ratio of alcohol to oil, reaction temperature, amount of catalyst, reaction time and agitation speed were also investigated to achieve best parameters setup for highest biodiesel yield. The results showed that the highest biodiesel yield of 94.05 was obtained at the 18:1 methanol to oil molar ratio, 100 °C reaction temperature, reaction time of 180 min, 5 catalyst dosage and agitation speed of 500 rpm. Moreover, the catalyst possesses high stability and can be recycled up to 5 consecutive biodiesel reactions without any loss in activity and additional treatment. © 2022 Elsevier Ltd Elsevier Ltd 2022 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85136491065&doi=10.1016%2fj.renene.2022.08.005&partnerID=40&md5=10af3c185c3ee0d3abf09b2c741c8662 Sahar, J. and Farooq, M. and Ramli, A. and Naeem, A. and Khattak, N.S. and Ghazi, Z.A. (2022) Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil. Renewable Energy, 198 . pp. 306-318. http://eprints.utp.edu.my/33491/ |
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In this study, TPA-impregnated SnO2@Co-ZIF catalyst was synthesized to employ for biodiesel production from locally available Mazari palm feedstock. The morphological and structural properties of the synthesized catalyst were studied by different analytical techniques such as Thermal gravimetric analysis (TGA/DTA), X-Ray diffraction analysis (XRD), Scanning electron microscopy (SEM), Energy dispersive X-Ray (EDX) analysis, Fourier transform infrared spectroscopy (FT-IR), Brunauer Emmett Teller (BET) and Temperature Programmed Desorption of ammonia (NH3�TPD) and carbon dioxide (CO2�TPD) to identify suitable catalyst formulation for efficient biodiesel production from Mazari palm oil. The important variables such as molar ratio of alcohol to oil, reaction temperature, amount of catalyst, reaction time and agitation speed were also investigated to achieve best parameters setup for highest biodiesel yield. The results showed that the highest biodiesel yield of 94.05 was obtained at the 18:1 methanol to oil molar ratio, 100 °C reaction temperature, reaction time of 180 min, 5 catalyst dosage and agitation speed of 500 rpm. Moreover, the catalyst possesses high stability and can be recycled up to 5 consecutive biodiesel reactions without any loss in activity and additional treatment. © 2022 Elsevier Ltd |
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| author |
Sahar, J. Farooq, M. Ramli, A. Naeem, A. Khattak, N.S. Ghazi, Z.A. |
| spellingShingle |
Sahar, J. Farooq, M. Ramli, A. Naeem, A. Khattak, N.S. Ghazi, Z.A. Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| author_facet |
Sahar, J. Farooq, M. Ramli, A. Naeem, A. Khattak, N.S. Ghazi, Z.A. |
| author_sort |
Sahar, J. |
| title |
Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| title_short |
Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| title_full |
Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| title_fullStr |
Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| title_full_unstemmed |
Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil |
| title_sort |
highly efficient heteropoly acid decorated sno2@co-zif nanocatalyst for sustainable biodiesel production from nannorrhops ritchiana seeds oil |
| publisher |
Elsevier Ltd |
| publishDate |
2022 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85136491065&doi=10.1016%2fj.renene.2022.08.005&partnerID=40&md5=10af3c185c3ee0d3abf09b2c741c8662 http://eprints.utp.edu.my/33491/ |
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