Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge

Among the water-polluting substances, heavy metals stand out due to their carcinogenic and toxic effects on the creatures and environment. This study aimed to scrutinize the effectiveness of sewage sludge-based activated carbon in the removal of copper and cadmium from aqueous solutions in column st...

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Main Authors: Al-Mahbashi, N., Kutty, S.R.M., Jagaba, A.H., Al-Nini, A., Ali, M., Saeed, A.A.H., Ghaleb, A.A.S., Rathnayake, U.
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Published: Hindawi Limited 2022
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85128326469&doi=10.1155%2f2022%2f3590462&partnerID=40&md5=638a7a70980fd2603ec52e0df7be340e
http://eprints.utp.edu.my/33257/
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spelling my.utp.eprints.332572022-07-06T08:28:19Z Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge Al-Mahbashi, N. Kutty, S.R.M. Jagaba, A.H. Al-Nini, A. Ali, M. Saeed, A.A.H. Ghaleb, A.A.S. Rathnayake, U. Among the water-polluting substances, heavy metals stand out due to their carcinogenic and toxic effects on the creatures and environment. This study aimed to scrutinize the effectiveness of sewage sludge-based activated carbon in the removal of copper and cadmium from aqueous solutions in column study. Detection of breakthrough curves and related parameters was conducted by varying bed depths (3, 6, and 9 cm). The solution with an initial metal concentration (IMC) of 100 ppm was pumped to the column at a flow rate of 2 mL/min. In the process of copper removal, the breakthrough points for depths 3 cm, 6 cm, and 9 cm were achieved at 10 min, 15 min, and 60 min, respectively, whereas breakthrough points of similar depths in cadmium removal process were achieved at 5 min, 10 min, and 30 min, respectively. Adsorption kinetics were analyzed using the Adams-Bohart, Yoon-Nelson, and Thomas kinetics models. The Adams-Bohart model described only the initial part of breakthrough curves. The Thomas model represented the adsorption process with coefficients of determination (R2) ranging between 0.90-0.95 for cadmium removal and 0.89-0.96 for copper removal, while the coefficients of determination of Yoon-Nelson ranged between 0.89-0.94 for cadmium and 0.95-0.97 for copper. Yoon-Nelson was fitted well with copper removal data, while removal of cadmium data was best described by the Thomas model. This study demonstrated that using sewage sludge-based activated carbon to remove heavy metals is an alternative, more cost-effective option to reach the objectives of sustainable development. © 2022 Najib Al-mahbashi et al. Hindawi Limited 2022 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85128326469&doi=10.1155%2f2022%2f3590462&partnerID=40&md5=638a7a70980fd2603ec52e0df7be340e Al-Mahbashi, N. and Kutty, S.R.M. and Jagaba, A.H. and Al-Nini, A. and Ali, M. and Saeed, A.A.H. and Ghaleb, A.A.S. and Rathnayake, U. (2022) Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge. Advances in Civil Engineering, 2022 . http://eprints.utp.edu.my/33257/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description Among the water-polluting substances, heavy metals stand out due to their carcinogenic and toxic effects on the creatures and environment. This study aimed to scrutinize the effectiveness of sewage sludge-based activated carbon in the removal of copper and cadmium from aqueous solutions in column study. Detection of breakthrough curves and related parameters was conducted by varying bed depths (3, 6, and 9 cm). The solution with an initial metal concentration (IMC) of 100 ppm was pumped to the column at a flow rate of 2 mL/min. In the process of copper removal, the breakthrough points for depths 3 cm, 6 cm, and 9 cm were achieved at 10 min, 15 min, and 60 min, respectively, whereas breakthrough points of similar depths in cadmium removal process were achieved at 5 min, 10 min, and 30 min, respectively. Adsorption kinetics were analyzed using the Adams-Bohart, Yoon-Nelson, and Thomas kinetics models. The Adams-Bohart model described only the initial part of breakthrough curves. The Thomas model represented the adsorption process with coefficients of determination (R2) ranging between 0.90-0.95 for cadmium removal and 0.89-0.96 for copper removal, while the coefficients of determination of Yoon-Nelson ranged between 0.89-0.94 for cadmium and 0.95-0.97 for copper. Yoon-Nelson was fitted well with copper removal data, while removal of cadmium data was best described by the Thomas model. This study demonstrated that using sewage sludge-based activated carbon to remove heavy metals is an alternative, more cost-effective option to reach the objectives of sustainable development. © 2022 Najib Al-mahbashi et al.
format Article
author Al-Mahbashi, N.
Kutty, S.R.M.
Jagaba, A.H.
Al-Nini, A.
Ali, M.
Saeed, A.A.H.
Ghaleb, A.A.S.
Rathnayake, U.
spellingShingle Al-Mahbashi, N.
Kutty, S.R.M.
Jagaba, A.H.
Al-Nini, A.
Ali, M.
Saeed, A.A.H.
Ghaleb, A.A.S.
Rathnayake, U.
Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
author_facet Al-Mahbashi, N.
Kutty, S.R.M.
Jagaba, A.H.
Al-Nini, A.
Ali, M.
Saeed, A.A.H.
Ghaleb, A.A.S.
Rathnayake, U.
author_sort Al-Mahbashi, N.
title Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
title_short Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
title_full Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
title_fullStr Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
title_full_unstemmed Column Study for Adsorption of Copper and Cadmium Using Activated Carbon Derived from Sewage Sludge
title_sort column study for adsorption of copper and cadmium using activated carbon derived from sewage sludge
publisher Hindawi Limited
publishDate 2022
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85128326469&doi=10.1155%2f2022%2f3590462&partnerID=40&md5=638a7a70980fd2603ec52e0df7be340e
http://eprints.utp.edu.my/33257/
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score 13.211869