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Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles

In phytosynthesis of gold nanoparticles (AuNPs), biomolecules play a vital role in biocapping the surface of particles and generating the electrostatic repulsive forces to inhibit their growth kinetics. However, estimation of bioactive compounds influencing their surface characteristics through form...

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Main Authors: Ahmad, T., Bustam, M.A., Suleman, H., Irfan, M., Iqbal, J., Asghar, H.M.A.
Format: Article
Published: Springer 2022
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85099957946&doi=10.1007%2fs10876-021-01999-5&partnerID=40&md5=4c7c70461b82ceef27c8501115e44ed9
http://eprints.utp.edu.my/32381/
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spelling my.utp.eprints.323812022-03-29T01:25:53Z Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles Ahmad, T. Bustam, M.A. Suleman, H. Irfan, M. Iqbal, J. Asghar, H.M.A. In phytosynthesis of gold nanoparticles (AuNPs), biomolecules play a vital role in biocapping the surface of particles and generating the electrostatic repulsive forces to inhibit their growth kinetics. However, estimation of bioactive compounds influencing their surface characteristics through formation of electric repulsive forces (Velec), Van der Waals attraction forces (Vvdw) and ultimately hindering their growth is still in the phase of obscurity. Current study, based on surface chemistry approach has been performed for identification of bioactive compounds in Elaeis guineensis leaves (EGL/OPL), acting as biocapping agents and directing the growth of AuNPs over a period of time. The quantitative estimation of interparticle interactions and modification in Ostwald ripening (MOR) model were also done to correlate the growth kinetic of AuNPs. The X-ray photoelectron spectroscopy (XPS) showed the major contribution of oxygen, carbon and nitrogen elements, corresponding to polyphenolic, carboxylic and amides, in biocapping the surface of AuNPs and directing their interparticle interactions associated with growth kinetics. The Velec forces were reduced with an enhancement in the Vvdw forces, depicting their major role in impeding growth of AuNPs. The MOR model exhibited an excellent agreement of predicted growth with experimental size enlargements of AuNPs, having 4.8 average absolute relative percentage error. © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature. Springer 2022 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85099957946&doi=10.1007%2fs10876-021-01999-5&partnerID=40&md5=4c7c70461b82ceef27c8501115e44ed9 Ahmad, T. and Bustam, M.A. and Suleman, H. and Irfan, M. and Iqbal, J. and Asghar, H.M.A. (2022) Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles. Journal of Cluster Science, 33 (2). pp. 557-565. http://eprints.utp.edu.my/32381/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description In phytosynthesis of gold nanoparticles (AuNPs), biomolecules play a vital role in biocapping the surface of particles and generating the electrostatic repulsive forces to inhibit their growth kinetics. However, estimation of bioactive compounds influencing their surface characteristics through formation of electric repulsive forces (Velec), Van der Waals attraction forces (Vvdw) and ultimately hindering their growth is still in the phase of obscurity. Current study, based on surface chemistry approach has been performed for identification of bioactive compounds in Elaeis guineensis leaves (EGL/OPL), acting as biocapping agents and directing the growth of AuNPs over a period of time. The quantitative estimation of interparticle interactions and modification in Ostwald ripening (MOR) model were also done to correlate the growth kinetic of AuNPs. The X-ray photoelectron spectroscopy (XPS) showed the major contribution of oxygen, carbon and nitrogen elements, corresponding to polyphenolic, carboxylic and amides, in biocapping the surface of AuNPs and directing their interparticle interactions associated with growth kinetics. The Velec forces were reduced with an enhancement in the Vvdw forces, depicting their major role in impeding growth of AuNPs. The MOR model exhibited an excellent agreement of predicted growth with experimental size enlargements of AuNPs, having 4.8 average absolute relative percentage error. © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature.
format Article
author Ahmad, T.
Bustam, M.A.
Suleman, H.
Irfan, M.
Iqbal, J.
Asghar, H.M.A.
spellingShingle Ahmad, T.
Bustam, M.A.
Suleman, H.
Irfan, M.
Iqbal, J.
Asghar, H.M.A.
Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
author_facet Ahmad, T.
Bustam, M.A.
Suleman, H.
Irfan, M.
Iqbal, J.
Asghar, H.M.A.
author_sort Ahmad, T.
title Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
title_short Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
title_full Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
title_fullStr Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
title_full_unstemmed Quantitative Estimation of Biocapped Surface Chemistry Driven Interparticle Interactions and Growth Kinetics of Gold Nanoparticles
title_sort quantitative estimation of biocapped surface chemistry driven interparticle interactions and growth kinetics of gold nanoparticles
publisher Springer
publishDate 2022
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85099957946&doi=10.1007%2fs10876-021-01999-5&partnerID=40&md5=4c7c70461b82ceef27c8501115e44ed9
http://eprints.utp.edu.my/32381/
_version_ 1738657379279437824
score 13.211869

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