Physical properties of ionic liquids consisting of 1-butyl-3- propanenitrile- and 1-decyl-3-propanenitrile imidazolium-based cations: Temperature dependence and influence of the anion
The effect of cationic and anionic chain lengths and temperature dependence of physical properties for a new series of 1-butyl-3-propanenitrile and 1-decyl-3-propanenitrile imidazolium-based ionic liquids were studied in a broad range of temperature (293.15 to 353.15) K at atmospheric pressure. The...
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| Format: | Article |
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American Chemical Society
2014
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| Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84898474269&doi=10.1021%2fje400849a&partnerID=40&md5=ef1e63d961b50e403048fb42d0d32da4 http://eprints.utp.edu.my/31281/ |
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| Summary: | The effect of cationic and anionic chain lengths and temperature dependence of physical properties for a new series of 1-butyl-3-propanenitrile and 1-decyl-3-propanenitrile imidazolium-based ionic liquids were studied in a broad range of temperature (293.15 to 353.15) K at atmospheric pressure. The present ILs show lower densities, higher viscosities, and comparable values of refractive index compared to those of analogous nitrile-functionalized ILs with different anions. The thermal expansion coefficient, compressibility coefficient, and molar refraction were calculated from the experimental values of density and refractive index. These ILs show a weak temperature dependency of the thermal expansion coefficient. © 2014 American Chemical Society. |
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