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Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks

Copper(II) bis(imidazolate) and copper(II)-zirconia(IV) bimetallic imidazolate were synthesized by metal oxides in aqueous solutions using acid catalyst procedure. The metal imidazolate frameworks were characterized by fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM)...

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Main Authors: Shaharun, M.S., Shaharun, S., Al-Shaibani, A.
Format: Conference or Workshop Item
Published: American Institute of Physics Inc. 2016
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005950839&doi=10.1063%2f1.4968111&partnerID=40&md5=6cc737cb6494a36c194d300677d4428a
http://eprints.utp.edu.my/30663/
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spelling my.utp.eprints.306632022-03-25T07:13:58Z Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks Shaharun, M.S. Shaharun, S. Al-Shaibani, A. Copper(II) bis(imidazolate) and copper(II)-zirconia(IV) bimetallic imidazolate were synthesized by metal oxides in aqueous solutions using acid catalyst procedure. The metal imidazolate frameworks were characterized by fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis) and N2 adsorption-desorption. The addition of ZrO2 increased the surface area and porosity of the metal organic frameworks. The modification of the copper(II) bis(imidazolate) with addition of ZrO2 enhances the visible light absorbance. The band gap of copper(II)-zirconia(II) bimetallic imidazolate is increased to 2.40 eV with more absorbance in the visible region compared to copper(II) bis(imidazolate). © 2016 Author(s). American Institute of Physics Inc. 2016 Conference or Workshop Item NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005950839&doi=10.1063%2f1.4968111&partnerID=40&md5=6cc737cb6494a36c194d300677d4428a Shaharun, M.S. and Shaharun, S. and Al-Shaibani, A. (2016) Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks. In: UNSPECIFIED. http://eprints.utp.edu.my/30663/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description Copper(II) bis(imidazolate) and copper(II)-zirconia(IV) bimetallic imidazolate were synthesized by metal oxides in aqueous solutions using acid catalyst procedure. The metal imidazolate frameworks were characterized by fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-Vis) and N2 adsorption-desorption. The addition of ZrO2 increased the surface area and porosity of the metal organic frameworks. The modification of the copper(II) bis(imidazolate) with addition of ZrO2 enhances the visible light absorbance. The band gap of copper(II)-zirconia(II) bimetallic imidazolate is increased to 2.40 eV with more absorbance in the visible region compared to copper(II) bis(imidazolate). © 2016 Author(s).
format Conference or Workshop Item
author Shaharun, M.S.
Shaharun, S.
Al-Shaibani, A.
spellingShingle Shaharun, M.S.
Shaharun, S.
Al-Shaibani, A.
Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
author_facet Shaharun, M.S.
Shaharun, S.
Al-Shaibani, A.
author_sort Shaharun, M.S.
title Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
title_short Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
title_full Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
title_fullStr Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
title_full_unstemmed Effect of zirconia on the physicochemical properties of copper (II) imidazolate frameworks
title_sort effect of zirconia on the physicochemical properties of copper (ii) imidazolate frameworks
publisher American Institute of Physics Inc.
publishDate 2016
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005950839&doi=10.1063%2f1.4968111&partnerID=40&md5=6cc737cb6494a36c194d300677d4428a
http://eprints.utp.edu.my/30663/
_version_ 1738657139133513728
score 13.211869

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