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Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction

Abstract: A catalytic transfer hydrogenation of castor oil using glycerol-based is a process of adding hydrogen to the castor oil to produce hydrogenated castor oil with the addition of 10 Pd/C as the catalyst and glycerol as a hydrogen donor. The reaction occurred at the reaction temperature of 178...

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Main Authors: Mohd Amin, U.S.B., Osman, N.B., Uemura, Y., Majid, N.M.N.A.
Format: Article
Published: Springer Science+Business Media B.V. 2020
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081956737&doi=10.1007%2fs12649-020-01010-8&partnerID=40&md5=a8dc9718a75dbc59026c8197ba0600cb
http://eprints.utp.edu.my/29893/
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spelling my.utp.eprints.298932022-03-25T03:05:31Z Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction Mohd Amin, U.S.B. Osman, N.B. Uemura, Y. Majid, N.M.N.A. Abstract: A catalytic transfer hydrogenation of castor oil using glycerol-based is a process of adding hydrogen to the castor oil to produce hydrogenated castor oil with the addition of 10 Pd/C as the catalyst and glycerol as a hydrogen donor. The reaction occurred at the reaction temperature of 178 °C for an hour. To prove whether glycerol can be one of the hydrogen donors like limonene that is commonly used, the research started by using pure glycerol as the hydrogen donor and as a control to determine the protocol. A direct heating apparatus connected with a reflux system was used for this experiment. The result from FTIR along with the melting point shows the formation of hydrogenated castor oil from this reaction. The increment in melting point value and the absence of C=C peak (1655.79 cm�1) from FTIR spectrum shows that the catalytic transfer hydrogenation successfully occurred. The melting point of the hydrogenated castor oil is 65 °C and the melting point of castor oil is � 7 °C. Therefore, it was proven that, the glycerol can be used as the hydrogen donor for the castor oil for a catalytic transfer hydrogenation reaction. Graphic abstract: Figure not available: see fulltext.. © 2020, Springer Nature B.V. Springer Science+Business Media B.V. 2020 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081956737&doi=10.1007%2fs12649-020-01010-8&partnerID=40&md5=a8dc9718a75dbc59026c8197ba0600cb Mohd Amin, U.S.B. and Osman, N.B. and Uemura, Y. and Majid, N.M.N.A. (2020) Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction. Waste and Biomass Valorization, 11 (10). pp. 5591-5597. http://eprints.utp.edu.my/29893/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description Abstract: A catalytic transfer hydrogenation of castor oil using glycerol-based is a process of adding hydrogen to the castor oil to produce hydrogenated castor oil with the addition of 10 Pd/C as the catalyst and glycerol as a hydrogen donor. The reaction occurred at the reaction temperature of 178 °C for an hour. To prove whether glycerol can be one of the hydrogen donors like limonene that is commonly used, the research started by using pure glycerol as the hydrogen donor and as a control to determine the protocol. A direct heating apparatus connected with a reflux system was used for this experiment. The result from FTIR along with the melting point shows the formation of hydrogenated castor oil from this reaction. The increment in melting point value and the absence of C=C peak (1655.79 cm�1) from FTIR spectrum shows that the catalytic transfer hydrogenation successfully occurred. The melting point of the hydrogenated castor oil is 65 °C and the melting point of castor oil is � 7 °C. Therefore, it was proven that, the glycerol can be used as the hydrogen donor for the castor oil for a catalytic transfer hydrogenation reaction. Graphic abstract: Figure not available: see fulltext.. © 2020, Springer Nature B.V.
format Article
author Mohd Amin, U.S.B.
Osman, N.B.
Uemura, Y.
Majid, N.M.N.A.
spellingShingle Mohd Amin, U.S.B.
Osman, N.B.
Uemura, Y.
Majid, N.M.N.A.
Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
author_facet Mohd Amin, U.S.B.
Osman, N.B.
Uemura, Y.
Majid, N.M.N.A.
author_sort Mohd Amin, U.S.B.
title Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
title_short Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
title_full Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
title_fullStr Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
title_full_unstemmed Catalytic Transfer Hydrogenation of Castor Oil Using Glycerol-Based Reaction
title_sort catalytic transfer hydrogenation of castor oil using glycerol-based reaction
publisher Springer Science+Business Media B.V.
publishDate 2020
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85081956737&doi=10.1007%2fs12649-020-01010-8&partnerID=40&md5=a8dc9718a75dbc59026c8197ba0600cb
http://eprints.utp.edu.my/29893/
_version_ 1738657030361579520
score 13.211869

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