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Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases

Borax and its calcined derivatives were used in pyrolytic valorization of tire tube rubber to produce high value oil and gases. This work involved the preparation and characterization of catalysts and optimization of the reaction parameters for the catalytic and non-catalytic pyrolysis of waste tire...

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Main Authors: Khan, A., Hussain, Z., Hussain, K., Naz, M.Y., Jan, M.R., Shukrullah, S., Ullah, S., Sulaiman, S.A., Hussien, M.
Format: Article
Published: Springer Science and Business Media B.V. 2021
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118581417&doi=10.1007%2fs11144-021-02108-3&partnerID=40&md5=d127942e1d58e6ed96a8f34f3c4b487f
http://eprints.utp.edu.my/29640/
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spelling my.utp.eprints.296402022-03-25T02:12:33Z Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases Khan, A. Hussain, Z. Hussain, K. Naz, M.Y. Jan, M.R. Shukrullah, S. Ullah, S. Sulaiman, S.A. Hussien, M. Borax and its calcined derivatives were used in pyrolytic valorization of tire tube rubber to produce high value oil and gases. This work involved the preparation and characterization of catalysts and optimization of the reaction parameters for the catalytic and non-catalytic pyrolysis of waste tire tube rubber. The derivatives of borax catalyst were prepared by calcining it at 600 °C, 800 °C and 1000 °C. The borax derivatives were labeled as borax-600, borax-800 and borax-1000 and used for the pyrolysis of waste rubber. The outcomes of the catalytic and thermal pyrolysis processes were compared to check the effectiveness of the borax derivatives as a catalyst. Both processes produced different quantities of oil, gas and char specifically in case of borax catalyzed and borax-1000 catalyzed reactions. The oil product of thermal pyrolysis was composed of 15 compounds while borax catalyzed pyrolysis produced oil with 14 compounds. On the other hand, all borax derivatives produced oil having nine compounds. The oil contained aliphatic and cyclic hydrocarbons along with small quantities of sulfur and phosphorous containing organic compounds. The results of distillation showed that thermal pyrolysis produced 83.80 volatile oil while borax catalyzed pyrolysis produced 83.84 volatile oil. The oil content decreased to 66.34 with an increase in borax calcination temperature. Similarly, thermal pyrolysis produced 12.56 residue while borax catalyzed reaction produced 16.10 residue. The residue decreased slightly with a rise in calcination temperature. © 2021, Akadémiai Kiadó, Budapest, Hungary. Springer Science and Business Media B.V. 2021 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118581417&doi=10.1007%2fs11144-021-02108-3&partnerID=40&md5=d127942e1d58e6ed96a8f34f3c4b487f Khan, A. and Hussain, Z. and Hussain, K. and Naz, M.Y. and Jan, M.R. and Shukrullah, S. and Ullah, S. and Sulaiman, S.A. and Hussien, M. (2021) Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases. Reaction Kinetics, Mechanisms and Catalysis, 134 (2). pp. 883-901. http://eprints.utp.edu.my/29640/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description Borax and its calcined derivatives were used in pyrolytic valorization of tire tube rubber to produce high value oil and gases. This work involved the preparation and characterization of catalysts and optimization of the reaction parameters for the catalytic and non-catalytic pyrolysis of waste tire tube rubber. The derivatives of borax catalyst were prepared by calcining it at 600 °C, 800 °C and 1000 °C. The borax derivatives were labeled as borax-600, borax-800 and borax-1000 and used for the pyrolysis of waste rubber. The outcomes of the catalytic and thermal pyrolysis processes were compared to check the effectiveness of the borax derivatives as a catalyst. Both processes produced different quantities of oil, gas and char specifically in case of borax catalyzed and borax-1000 catalyzed reactions. The oil product of thermal pyrolysis was composed of 15 compounds while borax catalyzed pyrolysis produced oil with 14 compounds. On the other hand, all borax derivatives produced oil having nine compounds. The oil contained aliphatic and cyclic hydrocarbons along with small quantities of sulfur and phosphorous containing organic compounds. The results of distillation showed that thermal pyrolysis produced 83.80 volatile oil while borax catalyzed pyrolysis produced 83.84 volatile oil. The oil content decreased to 66.34 with an increase in borax calcination temperature. Similarly, thermal pyrolysis produced 12.56 residue while borax catalyzed reaction produced 16.10 residue. The residue decreased slightly with a rise in calcination temperature. © 2021, Akadémiai Kiadó, Budapest, Hungary.
format Article
author Khan, A.
Hussain, Z.
Hussain, K.
Naz, M.Y.
Jan, M.R.
Shukrullah, S.
Ullah, S.
Sulaiman, S.A.
Hussien, M.
spellingShingle Khan, A.
Hussain, Z.
Hussain, K.
Naz, M.Y.
Jan, M.R.
Shukrullah, S.
Ullah, S.
Sulaiman, S.A.
Hussien, M.
Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
author_facet Khan, A.
Hussain, Z.
Hussain, K.
Naz, M.Y.
Jan, M.R.
Shukrullah, S.
Ullah, S.
Sulaiman, S.A.
Hussien, M.
author_sort Khan, A.
title Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
title_short Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
title_full Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
title_fullStr Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
title_full_unstemmed Evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
title_sort evaluation of the catalytic activity of borax and its calcined derivatives for pyrolytic valorization of waste tire tube rubber for production of oil and gases
publisher Springer Science and Business Media B.V.
publishDate 2021
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85118581417&doi=10.1007%2fs11144-021-02108-3&partnerID=40&md5=d127942e1d58e6ed96a8f34f3c4b487f
http://eprints.utp.edu.my/29640/
_version_ 1738656994597797888
score 13.222552

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