Thermal stability and flame-retardant characteristic of irradiated LDPE and composites
Magnesium hydroxide (MH) and alumina trihydrate (ATH) are extensively consumed as fillers in polyolefins to fabricate naturally responsive cables. Halogen-free wires, and especially cross-linked or thermoplastic elastomers, are further prevalent in worldwide use. The limited oxygen index (LOI), cone...
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Main Authors: | , , |
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Format: | Article |
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Springer
2020
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Online Access: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85077308495&doi=10.1007%2fs12034-019-2021-z&partnerID=40&md5=3ea2a311aaab88ab3827a380f79f20bd http://eprints.utp.edu.my/23275/ |
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Summary: | Magnesium hydroxide (MH) and alumina trihydrate (ATH) are extensively consumed as fillers in polyolefins to fabricate naturally responsive cables. Halogen-free wires, and especially cross-linked or thermoplastic elastomers, are further prevalent in worldwide use. The limited oxygen index (LOI), cone calorimeter, smoke density and thermogravimetry (TGA) experiments explain the thermal decomposition, flame-retardant and physical characteristics of samples. Results from studies of TGA, smoke emission and LOI testers showed that the thermal strength and flame-retardant characteristics of the samples containing MH compared with corresponding specimens containing ATH have superior thermal stability. The flame-retardant and heat resistance characteristics of samples were improved due to irradiation and the development of cross-linking bonds in the polymer framework. The results of the smoke density experiment show that adding MH to low-density polyethylene (LDPE) results in the lowest smoke density associated with LDPE and LDPE/ATH compounds. This study proved that the inclusion of MH and irradiation of specimens caused a greater thermal strength and also a superior flame-retardant polymeric product compared with the inclusion of ATH to similar irradiated specimens. These successes are useful and appropriate specifically for cable companies to deliver halogen-free flame-retardant cable materials. © 2020, Indian Academy of Sciences. |
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