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Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes

In the current study, new types of MMMs are fabricated by incorporating NH2-MIL-53(Al) filler into cellulose acetate (CA) polymer. Subsequently, crystallinity, morphology, thermal stability, functional groups and density measurement of the resultant MMMs were verified by using different analytical t...

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Main Authors: Mubashir, M., Yeong, Y.F., Lau, K.K., Chew, T.L., Norwahyu, J.
Format: Article
Published: Elsevier B.V. 2018
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041392597&doi=10.1016%2fj.seppur.2018.01.038&partnerID=40&md5=5c07343f60c0b44b348366bd256eba4e
http://eprints.utp.edu.my/20563/
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spelling my.utp.eprints.205632018-07-23T03:19:09Z Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes Mubashir, M. Yeong, Y.F. Lau, K.K. Chew, T.L. Norwahyu, J. In the current study, new types of MMMs are fabricated by incorporating NH2-MIL-53(Al) filler into cellulose acetate (CA) polymer. Subsequently, crystallinity, morphology, thermal stability, functional groups and density measurement of the resultant MMMs were verified by using different analytical tools. The results showed that the presence of NH2-MIL-53(Al) in CA matrix had enhanced the CO2 permeability, CO2/N2 and CO2/CH4 ideal selectivities from 15.5 Barrer to 52.6 Barrer, 8.8 to 23.4 and 10.7 to 28.7, respectively. The present study revealed that the addition of 15 wt NH2-MIL-53(Al) MOF into the CA matrix resulted in highest enhancement of FFV. Furthermore, MMM loaded with 15 wt NH2-MIL-53(Al) demonstrated highest CO2 permeability as well as CO2/CH4 and CO2/N2 selectivities of 52.6 Barrer, 28.7 and 23.4, respectively. Besides, the resultant MMM showed CO2 plasticization resistance of up to 30 bar, which is 200 increment in comparison of pristine CA membrane which is only 10 bar. This work also revealed that the resultant MMMs showed significantly higher CO2 separation performance compared to the results previously reported for CA-based MMMs. Thus, it can be concluded that the MMMs fabricated in the present work has potential for CO2 removal from the flue gas and natural gas at industrial scale. © 2018 Elsevier B.V. Elsevier B.V. 2018 Article PeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041392597&doi=10.1016%2fj.seppur.2018.01.038&partnerID=40&md5=5c07343f60c0b44b348366bd256eba4e Mubashir, M. and Yeong, Y.F. and Lau, K.K. and Chew, T.L. and Norwahyu, J. (2018) Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes. Separation and Purification Technology, 199 . pp. 140-151. http://eprints.utp.edu.my/20563/
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Institutional Repository
url_provider http://eprints.utp.edu.my/
description In the current study, new types of MMMs are fabricated by incorporating NH2-MIL-53(Al) filler into cellulose acetate (CA) polymer. Subsequently, crystallinity, morphology, thermal stability, functional groups and density measurement of the resultant MMMs were verified by using different analytical tools. The results showed that the presence of NH2-MIL-53(Al) in CA matrix had enhanced the CO2 permeability, CO2/N2 and CO2/CH4 ideal selectivities from 15.5 Barrer to 52.6 Barrer, 8.8 to 23.4 and 10.7 to 28.7, respectively. The present study revealed that the addition of 15 wt NH2-MIL-53(Al) MOF into the CA matrix resulted in highest enhancement of FFV. Furthermore, MMM loaded with 15 wt NH2-MIL-53(Al) demonstrated highest CO2 permeability as well as CO2/CH4 and CO2/N2 selectivities of 52.6 Barrer, 28.7 and 23.4, respectively. Besides, the resultant MMM showed CO2 plasticization resistance of up to 30 bar, which is 200 increment in comparison of pristine CA membrane which is only 10 bar. This work also revealed that the resultant MMMs showed significantly higher CO2 separation performance compared to the results previously reported for CA-based MMMs. Thus, it can be concluded that the MMMs fabricated in the present work has potential for CO2 removal from the flue gas and natural gas at industrial scale. © 2018 Elsevier B.V.
format Article
author Mubashir, M.
Yeong, Y.F.
Lau, K.K.
Chew, T.L.
Norwahyu, J.
spellingShingle Mubashir, M.
Yeong, Y.F.
Lau, K.K.
Chew, T.L.
Norwahyu, J.
Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
author_facet Mubashir, M.
Yeong, Y.F.
Lau, K.K.
Chew, T.L.
Norwahyu, J.
author_sort Mubashir, M.
title Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
title_short Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
title_full Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
title_fullStr Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
title_full_unstemmed Efficient CO2/N2 and CO2/CH4 separation using NH2-MIL-53(Al)/cellulose acetate (CA) mixed matrix membranes
title_sort efficient co2/n2 and co2/ch4 separation using nh2-mil-53(al)/cellulose acetate (ca) mixed matrix membranes
publisher Elsevier B.V.
publishDate 2018
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85041392597&doi=10.1016%2fj.seppur.2018.01.038&partnerID=40&md5=5c07343f60c0b44b348366bd256eba4e
http://eprints.utp.edu.my/20563/
_version_ 1738656201878536192
score 13.211869

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