Cover Image

Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation

The performance of cobalt supported on mesoporous alumina (MA) under the influence of reaction temperature (923 K–1073 K) and reactant partial pressure (10 kPa–40 kPa) for CO2–CH4 reforming was executed by using a tubular fixed-bed reactor. 10%Co/MA exhibited great catalytic performance (XCH=70.9%,...

Full description

Saved in:
Bibliographic Details
Main Authors: Bahari, Mahadi B., Setiabudi, Herma Dina, Nguyen, Trinh Duy, Abdul Jalil, Aishah, Razali, Nurul Aini, Vo, Dai-Viet N.
Format: Article
Published: Elsevier Ltd 2021
Subjects:
TP Chemical technology
Online Access:http://eprints.utm.my/id/eprint/97542/
http://dx.doi.org/10.1016/j.ijhydene.2020.04.130
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.utm.97542
record_format eprints
spelling my.utm.975422022-10-17T06:18:27Z http://eprints.utm.my/id/eprint/97542/ Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation Bahari, Mahadi B. Setiabudi, Herma Dina Nguyen, Trinh Duy Abdul Jalil, Aishah Razali, Nurul Aini Vo, Dai-Viet N. TP Chemical technology The performance of cobalt supported on mesoporous alumina (MA) under the influence of reaction temperature (923 K–1073 K) and reactant partial pressure (10 kPa–40 kPa) for CO2–CH4 reforming was executed by using a tubular fixed-bed reactor. 10%Co/MA exhibited great catalytic performance (XCH=70.9%, XCO=71.7% andDa=1.3%), credited to the well dispersion of Co within pore MA, strong metal-support interaction, and MA confinement ability. Based on Langmuir-Hinshelwood kinetic analysis, the dissociative adsorption of both reactants on a single Co active site was selected for this study. The lower value of activation energy (28.9 kJ mol-1) suggested that Co particles were finely scattered on the MA surface. Regardless of carbon types, the amount of coke accumulated on the spent 10%Co/MA within 8 h of CO2–CH4 reforming was inhibited due to fine Co distribution inside MA structure, as well as lessened with the raise of reforming temperature from 923 to 1073 K due to improvement in reverse Boudouard reaction. Elsevier Ltd 2021 Article PeerReviewed Bahari, Mahadi B. and Setiabudi, Herma Dina and Nguyen, Trinh Duy and Abdul Jalil, Aishah and Razali, Nurul Aini and Vo, Dai-Viet N. (2021) Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation. International Journal of Hydrogen Energy, 46 (48). pp. 24742-24753. ISSN 0360-3199 http://dx.doi.org/10.1016/j.ijhydene.2020.04.130 DOI : 10.1016/j.ijhydene.2020.04.130
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Bahari, Mahadi B.
Setiabudi, Herma Dina
Nguyen, Trinh Duy
Abdul Jalil, Aishah
Razali, Nurul Aini
Vo, Dai-Viet N.
Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
description The performance of cobalt supported on mesoporous alumina (MA) under the influence of reaction temperature (923 K–1073 K) and reactant partial pressure (10 kPa–40 kPa) for CO2–CH4 reforming was executed by using a tubular fixed-bed reactor. 10%Co/MA exhibited great catalytic performance (XCH=70.9%, XCO=71.7% andDa=1.3%), credited to the well dispersion of Co within pore MA, strong metal-support interaction, and MA confinement ability. Based on Langmuir-Hinshelwood kinetic analysis, the dissociative adsorption of both reactants on a single Co active site was selected for this study. The lower value of activation energy (28.9 kJ mol-1) suggested that Co particles were finely scattered on the MA surface. Regardless of carbon types, the amount of coke accumulated on the spent 10%Co/MA within 8 h of CO2–CH4 reforming was inhibited due to fine Co distribution inside MA structure, as well as lessened with the raise of reforming temperature from 923 to 1073 K due to improvement in reverse Boudouard reaction.
format Article
author Bahari, Mahadi B.
Setiabudi, Herma Dina
Nguyen, Trinh Duy
Abdul Jalil, Aishah
Razali, Nurul Aini
Vo, Dai-Viet N.
author_facet Bahari, Mahadi B.
Setiabudi, Herma Dina
Nguyen, Trinh Duy
Abdul Jalil, Aishah
Razali, Nurul Aini
Vo, Dai-Viet N.
author_sort Bahari, Mahadi B.
title Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
title_short Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
title_full Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
title_fullStr Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
title_full_unstemmed Hydrogen production via CO2single bondCH4 reforming over cobalt-supported mesoporous alumina: A kinetic evaluation
title_sort hydrogen production via co2single bondch4 reforming over cobalt-supported mesoporous alumina: a kinetic evaluation
publisher Elsevier Ltd
publishDate 2021
url http://eprints.utm.my/id/eprint/97542/
http://dx.doi.org/10.1016/j.ijhydene.2020.04.130
_version_ 1748180474186956800
score 13.211869

Similar Items