Staff View: Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte

Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte

The electrochemical thermoelectric effect is capable of generating Seebeck and conductivity from a temperature gradient through redox reaction at the electrode. Conventional spin Seebeck effect (SSE) is the generation of spin voltage by solid coupling magnetic thin film in presence of magnetic field...

Full description

Saved in:

Bibliographic Details
Main Authors:	Hasnan, M. M. I. M., Noor, I. S. M., Nayan, N., Ahmad, M. K., Said, S. M., Sabri, M. F. M., Salleh, M. F. M., Ali, M. S. M., Zin, R. M.
Format:	Article
Published:	Wiley-Blackwell 2021
Subjects:	TK Electrical engineering. Electronics Nuclear engineering
Online Access:	http://eprints.utm.my/id/eprint/96587/ http://dx.doi.org/10.1016/j.memsci.2021.119707
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my.utm.96587
record_format	eprints
spelling	my.utm.965872022-07-28T07:10:01Z http://eprints.utm.my/id/eprint/96587/ Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte Hasnan, M. M. I. M. Noor, I. S. M. Nayan, N. Ahmad, M. K. Said, S. M. Sabri, M. F. M. Salleh, M. F. M. Ali, M. S. M. Zin, R. M. TK Electrical engineering. Electronics Nuclear engineering The electrochemical thermoelectric effect is capable of generating Seebeck and conductivity from a temperature gradient through redox reaction at the electrode. Conventional spin Seebeck effect (SSE) is the generation of spin voltage by solid coupling magnetic thin film in presence of magnetic field and temperature gradient. In this study, we demonstrate an enhancement of a magnetic free SSE of Fe (II) reverse spin-crossover in electrolyte using 1% PMMA polymer additive in form of polymer electrolyte. The reverse spin effect of Fe (II) complex, which is confirmed by SQUID magnetometer analysis and DFT simulation, is able to produce magnetic free SSE in solution. A unique electrochemical behavior is found in form of SSE Fe (II) polymer electrolyte that is elucidated using cyclic voltammetry, electrochemical impedance spectroscopy, and UV-Vis analysis. The polymer electrolyte that possesses strong spin Seebeck produces a maximum Seebeck coefficient and conductivity of 124 % and 233 % higher than that weak SSE and conventional liquid electrolyte. The spin Seebeck produces a high number of carrier density through fast diffusion at high spin state, and the opposite charge properties trend at low spin state. Cryo-TEM analysis had shown that the generation of spin Seeebeck effect of the Fe (II) complex in solution also involves reverse spherical micelles formation. Thus, this study highlights the finding of a rare magnetic free spin Seebeck generation in polymer electrolyte that having potential for waste heat recycles, heat sensors, and thermal switches applications upon development. Wiley-Blackwell 2021 Article PeerReviewed Hasnan, M. M. I. M. and Noor, I. S. M. and Nayan, N. and Ahmad, M. K. and Said, S. M. and Sabri, M. F. M. and Salleh, M. F. M. and Ali, M. S. M. and Zin, R. M. (2021) Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte. Applied Organometallic Chemistry, 35 (8). p. 119707. ISSN 0268-2605 (Submitted) http://dx.doi.org/10.1016/j.memsci.2021.119707 DOI: 10.1016/j.memsci.2021.119707
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
topic	TK Electrical engineering. Electronics Nuclear engineering
spellingShingle	TK Electrical engineering. Electronics Nuclear engineering Hasnan, M. M. I. M. Noor, I. S. M. Nayan, N. Ahmad, M. K. Said, S. M. Sabri, M. F. M. Salleh, M. F. M. Ali, M. S. M. Zin, R. M. Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
description	The electrochemical thermoelectric effect is capable of generating Seebeck and conductivity from a temperature gradient through redox reaction at the electrode. Conventional spin Seebeck effect (SSE) is the generation of spin voltage by solid coupling magnetic thin film in presence of magnetic field and temperature gradient. In this study, we demonstrate an enhancement of a magnetic free SSE of Fe (II) reverse spin-crossover in electrolyte using 1% PMMA polymer additive in form of polymer electrolyte. The reverse spin effect of Fe (II) complex, which is confirmed by SQUID magnetometer analysis and DFT simulation, is able to produce magnetic free SSE in solution. A unique electrochemical behavior is found in form of SSE Fe (II) polymer electrolyte that is elucidated using cyclic voltammetry, electrochemical impedance spectroscopy, and UV-Vis analysis. The polymer electrolyte that possesses strong spin Seebeck produces a maximum Seebeck coefficient and conductivity of 124 % and 233 % higher than that weak SSE and conventional liquid electrolyte. The spin Seebeck produces a high number of carrier density through fast diffusion at high spin state, and the opposite charge properties trend at low spin state. Cryo-TEM analysis had shown that the generation of spin Seeebeck effect of the Fe (II) complex in solution also involves reverse spherical micelles formation. Thus, this study highlights the finding of a rare magnetic free spin Seebeck generation in polymer electrolyte that having potential for waste heat recycles, heat sensors, and thermal switches applications upon development.
format	Article
author	Hasnan, M. M. I. M. Noor, I. S. M. Nayan, N. Ahmad, M. K. Said, S. M. Sabri, M. F. M. Salleh, M. F. M. Ali, M. S. M. Zin, R. M.
author_facet	Hasnan, M. M. I. M. Noor, I. S. M. Nayan, N. Ahmad, M. K. Said, S. M. Sabri, M. F. M. Salleh, M. F. M. Ali, M. S. M. Zin, R. M.
author_sort	Hasnan, M. M. I. M.
title	Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
title_short	Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
title_full	Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
title_fullStr	Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
title_full_unstemmed	Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte
title_sort	enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using pmma polymer electrolyte
publisher	Wiley-Blackwell
publishDate	2021
url	http://eprints.utm.my/id/eprint/96587/ http://dx.doi.org/10.1016/j.memsci.2021.119707
_version_	1739828100854710272
score	13.211869

Enhancement of spin seebeck effect of reverse spin crossover fe (ii) micellar charge transport using PMMA polymer electrolyte

Similar Items