Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption

The adsorption of surfactants from aqueous solutions in porous media is essential in enhanced oil recovery (EOR) from oil reservoirs. Surfactant loss that is due to adsorption by the reservoir rocks weakens the efficiency of the chemical slurry that is injected and decreases the oil-water interfacia...

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Main Authors: Daud, N. M. A. N., W. Jaafar, W. M. K., Ismail, N., Junin, Radzuan, A.. Manan, M., Idris, A. K.
Format: Conference or Workshop Item
Language:English
Published: 2021
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Online Access:http://eprints.utm.my/id/eprint/96322/1/RadzuanJunin2021_UtilizingLignosulfonatefromCoconutHusk.pdf
http://eprints.utm.my/id/eprint/96322/
http://dx.doi.org/10.1088/1755-1315/765/1/012021
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spelling my.utm.963222022-07-17T07:13:09Z http://eprints.utm.my/id/eprint/96322/ Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption Daud, N. M. A. N. W. Jaafar, W. M. K. Ismail, N. Junin, Radzuan A.. Manan, M. Idris, A. K. Q Science (General) TP Chemical technology The adsorption of surfactants from aqueous solutions in porous media is essential in enhanced oil recovery (EOR) from oil reservoirs. Surfactant loss that is due to adsorption by the reservoir rocks weakens the efficiency of the chemical slurry that is injected and decreases the oil-water interfacial tension (IFT). One of the ways to reduce the reduction is by using a sacrificial agent. This project will focus on utilizing the lignosulfonate (LS) from coconut husk as a sacrificial agent to reduce the surfactant adsorption. Lignin was extracted from coconut husk before sulfonated using sodium sulphite, Na2SO3 to form lignosulfonate. Fourier transform infrared (FTIR) spectroscopy was used to characterize the lignin and lignosulfonate and compare them with the commercial product. The batch experiment then conducted using a clay mineral of illite as the adsorbent. Two types of surfactants were studied; anionic (Sodium Dodecyl Sulfate-SDS) and non-ionic (4-octylphenol polyethoxylate-TX100). The amount of adsorbed surfactant was determined by measuring the surfactant critical micelle concentration (CMC) before and after the adsorption tests. The result in the batch experiment shows that LS reduced the surfactant adsorption on illite by about 54.2% for SDS and 42.6% for TX100. This showed that lignosulfonate has the potential as a sacrificial agent to minimize the surfactant adsorption, and agriculture waste like coconut husk can be utilized for this purpose. 2021-05-24 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/96322/1/RadzuanJunin2021_UtilizingLignosulfonatefromCoconutHusk.pdf Daud, N. M. A. N. and W. Jaafar, W. M. K. and Ismail, N. and Junin, Radzuan and A.. Manan, M. and Idris, A. K. (2021) Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption. In: 1st International Conference on Biomass Utilization and Sustainable Energy 2020, ICoBiomasSE 2020, 15 December 2020 - 16 December 2020, Virtual, Online. http://dx.doi.org/10.1088/1755-1315/765/1/012021
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic Q Science (General)
TP Chemical technology
spellingShingle Q Science (General)
TP Chemical technology
Daud, N. M. A. N.
W. Jaafar, W. M. K.
Ismail, N.
Junin, Radzuan
A.. Manan, M.
Idris, A. K.
Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
description The adsorption of surfactants from aqueous solutions in porous media is essential in enhanced oil recovery (EOR) from oil reservoirs. Surfactant loss that is due to adsorption by the reservoir rocks weakens the efficiency of the chemical slurry that is injected and decreases the oil-water interfacial tension (IFT). One of the ways to reduce the reduction is by using a sacrificial agent. This project will focus on utilizing the lignosulfonate (LS) from coconut husk as a sacrificial agent to reduce the surfactant adsorption. Lignin was extracted from coconut husk before sulfonated using sodium sulphite, Na2SO3 to form lignosulfonate. Fourier transform infrared (FTIR) spectroscopy was used to characterize the lignin and lignosulfonate and compare them with the commercial product. The batch experiment then conducted using a clay mineral of illite as the adsorbent. Two types of surfactants were studied; anionic (Sodium Dodecyl Sulfate-SDS) and non-ionic (4-octylphenol polyethoxylate-TX100). The amount of adsorbed surfactant was determined by measuring the surfactant critical micelle concentration (CMC) before and after the adsorption tests. The result in the batch experiment shows that LS reduced the surfactant adsorption on illite by about 54.2% for SDS and 42.6% for TX100. This showed that lignosulfonate has the potential as a sacrificial agent to minimize the surfactant adsorption, and agriculture waste like coconut husk can be utilized for this purpose.
format Conference or Workshop Item
author Daud, N. M. A. N.
W. Jaafar, W. M. K.
Ismail, N.
Junin, Radzuan
A.. Manan, M.
Idris, A. K.
author_facet Daud, N. M. A. N.
W. Jaafar, W. M. K.
Ismail, N.
Junin, Radzuan
A.. Manan, M.
Idris, A. K.
author_sort Daud, N. M. A. N.
title Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
title_short Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
title_full Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
title_fullStr Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
title_full_unstemmed Utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
title_sort utilizing lignosulfonate from coconut husk as sacrificial agent to reduce surfactant adsorption
publishDate 2021
url http://eprints.utm.my/id/eprint/96322/1/RadzuanJunin2021_UtilizingLignosulfonatefromCoconutHusk.pdf
http://eprints.utm.my/id/eprint/96322/
http://dx.doi.org/10.1088/1755-1315/765/1/012021
_version_ 1739828062967562240
score 13.211869