Effects of TiO2 phase and nanostructures as photoanode on the performance of dye-sensitized solar cells

In this study, different titanium dioxide (TiO2) nanostructures and phase were investigated as photoanode film for application in dye-sensitized solar cells. Rutile TiO2 nanorods (NRs)-nanotrees (NTs) and TiO2 NRs-microcauliflowers (MCFs) were synthesized via hydrothermal method for different time....

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Main Authors: Muqoyyanah, Muqoyyanah, Suriani, A. B., Mohamed, A., Hashim, N., Mamat, M. H., Ahmad, M. K., Othman, M. H. D., Mohamed, M. A., Nurhafizah, M. D., Birowosuto, M. D., Soga, T.
Format: Article
Published: Springer 2021
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Online Access:http://eprints.utm.my/id/eprint/94963/
http://dx.doi.org/10.1007/s12034-020-02302-4
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Summary:In this study, different titanium dioxide (TiO2) nanostructures and phase were investigated as photoanode film for application in dye-sensitized solar cells. Rutile TiO2 nanorods (NRs)-nanotrees (NTs) and TiO2 NRs-microcauliflowers (MCFs) were synthesized via hydrothermal method for different time. The mixed phase of rutile-anatase film was fabricated by applying TiO2 nanoparticles paste on the synthesized TiO2 NRs-NTs via squeegee method. The counter electrode film was fabricated by spraying deposition and sputtering methods of reduced graphene oxide–multi-walled carbon nanotubes and platinum, respectively. Solar simulator measurement revealed that higher energy conversion efficiency (1.420%) and short-circuit current density (3.584 mA cm-2) were achieved by using rutile TiO2 NRs-MCFs film. The utilization of a thick rutile film with microparticle structures increases dye adsorption, and thus enhances the electron excitation. Graphic abstract: [Figure not available: see fulltext.].