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Toluene side chain alkylation with methanol over silica catalyst

MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in...

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Main Authors: Aziz, M. A. H., Jalil, A. A., Rahman, A. F. A., Fatah, N. A. A., Izan, S. M., Hussain, I., Hambali, H. U.
Format: Conference or Workshop Item
Language:English
Published: 2020
Subjects:
QD Chemistry
Online Access:http://eprints.utm.my/id/eprint/92339/1/MAHAziz2020_TolueneSideChainAlkylationWithMethanol.pdf
http://eprints.utm.my/id/eprint/92339/
http://dx.doi.org/10.1088/1757-899X/808/1/012004
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spelling my.utm.923392021-09-28T07:38:48Z http://eprints.utm.my/id/eprint/92339/ Toluene side chain alkylation with methanol over silica catalyst Aziz, M. A. H. Jalil, A. A. Rahman, A. F. A. Fatah, N. A. A. Izan, S. M. Hussain, I. Hambali, H. U. QD Chemistry MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO2 catalyst revealed that MSN possessed higher basic sites than SiO2. N2 adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO2 as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO2 catalyst. 2020 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/92339/1/MAHAziz2020_TolueneSideChainAlkylationWithMethanol.pdf Aziz, M. A. H. and Jalil, A. A. and Rahman, A. F. A. and Fatah, N. A. A. and Izan, S. M. and Hussain, I. and Hambali, H. U. (2020) Toluene side chain alkylation with methanol over silica catalyst. In: 8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019, 27 - 28 November 2019, Kuala Lumpur, Malaysia. http://dx.doi.org/10.1088/1757-899X/808/1/012004
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Aziz, M. A. H.
Jalil, A. A.
Rahman, A. F. A.
Fatah, N. A. A.
Izan, S. M.
Hussain, I.
Hambali, H. U.
Toluene side chain alkylation with methanol over silica catalyst
description MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO2 catalyst revealed that MSN possessed higher basic sites than SiO2. N2 adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO2 as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO2 catalyst.
format Conference or Workshop Item
author Aziz, M. A. H.
Jalil, A. A.
Rahman, A. F. A.
Fatah, N. A. A.
Izan, S. M.
Hussain, I.
Hambali, H. U.
author_facet Aziz, M. A. H.
Jalil, A. A.
Rahman, A. F. A.
Fatah, N. A. A.
Izan, S. M.
Hussain, I.
Hambali, H. U.
author_sort Aziz, M. A. H.
title Toluene side chain alkylation with methanol over silica catalyst
title_short Toluene side chain alkylation with methanol over silica catalyst
title_full Toluene side chain alkylation with methanol over silica catalyst
title_fullStr Toluene side chain alkylation with methanol over silica catalyst
title_full_unstemmed Toluene side chain alkylation with methanol over silica catalyst
title_sort toluene side chain alkylation with methanol over silica catalyst
publishDate 2020
url http://eprints.utm.my/id/eprint/92339/1/MAHAziz2020_TolueneSideChainAlkylationWithMethanol.pdf
http://eprints.utm.my/id/eprint/92339/
http://dx.doi.org/10.1088/1757-899X/808/1/012004
_version_ 1712285080545656832
score 13.211869

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