Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass
This paper reports the luminescence potential of the dysprosium ion (Dy3+)-doped (varying contents from 0.1 to 1.0 mol%) magnesium borate glasses prepared by the melt-quenching method. As-quenched samples were characterized systematically to determine the effects of various Dy3+ contents on their st...
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my.utm.907482021-04-30T14:57:17Z http://eprints.utm.my/id/eprint/90748/ Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass Ichoja, A. Hashim, S. Ghoshal, S. K. Hashim, I. H. QC Physics This paper reports the luminescence potential of the dysprosium ion (Dy3+)-doped (varying contents from 0.1 to 1.0 mol%) magnesium borate glasses prepared by the melt-quenching method. As-quenched samples were characterized systematically to determine the effects of various Dy3+ contents on their structure, physical and optical traits. The Judd−Ofelt (J−O) intensity parameters (Ω2, Ω4, Ω6) and radiative properties of the best sample (with 0.7 mol% of Dy3+ doping) was evaluated to complement the experimental optical data. The studied glasses revealed three luminescence emission peaks at 382 nm (4F9/2→6H15/2, intense Blue), 572 nm (4F9/2→6H15/2, intense Yellow) and 661 nm (4F9/2→6H11/2, weak Red) under the excitation wavelength of 347 nm. The emission intensity was first increased up to the Dy3+ content of 0.7 mol% and then quenched. The observed luminescence intensity quenching was due to the resonant energy transfer from the excited state to the neighbouring ground state of Dy3+. The obtained high value of Ω2 signified the strong degree of covalency between the Dy3+ and ligand environment. The optimum glass sample (with 0.7 mol% of Dy3+) showed higher values of the branching ratio and stimulated emission cross-cross section for the 4F9/2→6H15/2 (yellow) emission transition, indicating its potential as bright yellow luminescent material and high gain visible laser applications. Elsevier B.V. 2020-08 Article PeerReviewed Ichoja, A. and Hashim, S. and Ghoshal, S. K. and Hashim, I. H. (2020) Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass. Chinese Journal of Physics, 66 . pp. 307-317. ISSN 0577-9073 http://dx.doi.org/10.1016/j.cjph.2020.03.029 DOI:10.1016/j.cjph.2020.03.029 |
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QC Physics Ichoja, A. Hashim, S. Ghoshal, S. K. Hashim, I. H. Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
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This paper reports the luminescence potential of the dysprosium ion (Dy3+)-doped (varying contents from 0.1 to 1.0 mol%) magnesium borate glasses prepared by the melt-quenching method. As-quenched samples were characterized systematically to determine the effects of various Dy3+ contents on their structure, physical and optical traits. The Judd−Ofelt (J−O) intensity parameters (Ω2, Ω4, Ω6) and radiative properties of the best sample (with 0.7 mol% of Dy3+ doping) was evaluated to complement the experimental optical data. The studied glasses revealed three luminescence emission peaks at 382 nm (4F9/2→6H15/2, intense Blue), 572 nm (4F9/2→6H15/2, intense Yellow) and 661 nm (4F9/2→6H11/2, weak Red) under the excitation wavelength of 347 nm. The emission intensity was first increased up to the Dy3+ content of 0.7 mol% and then quenched. The observed luminescence intensity quenching was due to the resonant energy transfer from the excited state to the neighbouring ground state of Dy3+. The obtained high value of Ω2 signified the strong degree of covalency between the Dy3+ and ligand environment. The optimum glass sample (with 0.7 mol% of Dy3+) showed higher values of the branching ratio and stimulated emission cross-cross section for the 4F9/2→6H15/2 (yellow) emission transition, indicating its potential as bright yellow luminescent material and high gain visible laser applications. |
| format |
Article |
| author |
Ichoja, A. Hashim, S. Ghoshal, S. K. Hashim, I. H. |
| author_facet |
Ichoja, A. Hashim, S. Ghoshal, S. K. Hashim, I. H. |
| author_sort |
Ichoja, A. |
| title |
Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
| title_short |
Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
| title_full |
Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
| title_fullStr |
Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
| title_full_unstemmed |
Absorption and luminescence spectral analysis of Dy3+-doped magnesium borate glass |
| title_sort |
absorption and luminescence spectral analysis of dy3+-doped magnesium borate glass |
| publisher |
Elsevier B.V. |
| publishDate |
2020 |
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http://eprints.utm.my/id/eprint/90748/ http://dx.doi.org/10.1016/j.cjph.2020.03.029 |
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1698696979843907584 |
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13.211869 |