Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
The present study evaluates the effect of sodium hydroxide concentrations on strength, bond properties, reaction products and the microstructures of binary blended alkali-activated volcanic natural pozzolan and limestone powder (AANL) mortar. Six AANL mortar were prepared with alkaline activators of...
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| Main Authors: | , , , , |
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| Format: | Article |
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Elsevier Ltd
2021
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| Subjects: | |
| Online Access: | http://eprints.utm.my/id/eprint/90241/ http://dx.doi.org/10.1016/j.conbuildmat.2020.121530 |
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| Summary: | The present study evaluates the effect of sodium hydroxide concentrations on strength, bond properties, reaction products and the microstructures of binary blended alkali-activated volcanic natural pozzolan and limestone powder (AANL) mortar. Six AANL mortar were prepared with alkaline activators of 4–14 M NaOH(aq) and Na2SiO3(aq) such that the activators ratio was 1:1. Curing was done at 75 °C for 24 h duration. The maximum 90-day compressive strength of 31.3 MPa was achieved with 10 M NaOH(aq) while 76% of the strength could be achieved within three days when 10 M NaOH was used. The 28-day tensile strength of 2.32 MPa was achieved with 14 M NaOH(aq). XRD characterizations revealed that activation with a strong concentration of sodium hydroxide (10 M NaOH(aq)) led to the formation of anorthite (CaAl2Si2O8) and gehlenite (Ca0.Al2O3SiO2). SEM + EDX indicated that strong alkali (10 M NaOH) enhanced microstructural density compared to that of mild alkali (4 M NaOH(aq)). |
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