Staff View: Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance

Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance

A highly active and robust fibrous spherical ZSM-5-supported nickel catalyst with different promoters (Mg, Ca, Ta, Ga) have been synthesised by microemulsion method for dry reforming of methane (DRM). The structural framework provided by the unique fibrous spherical ZSM-5 aided confinement of Ni par...

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Main Authors:	Hambali, U., Jalil, A. A., Abdulrasheed, A. A., Siang, T. J., Abdullah, T. A. T., Ahmad, A., Vo, D. V. N.
Format:	Article
Published:	Wiley-Blackwell 2020
Subjects:	TP Chemical technology
Online Access:	http://eprints.utm.my/id/eprint/86610/ https://dx.doi.org/10.1002/er.5327
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id	my.utm.86610
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spelling	my.utm.866102020-09-30T08:57:58Z http://eprints.utm.my/id/eprint/86610/ Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance Hambali, U. Jalil, A. A. Abdulrasheed, A. A. Siang, T. J. Abdullah, T. A. T. Ahmad, A. Vo, D. V. N. TP Chemical technology A highly active and robust fibrous spherical ZSM-5-supported nickel catalyst with different promoters (Mg, Ca, Ta, Ga) have been synthesised by microemulsion method for dry reforming of methane (DRM). The structural framework provided by the unique fibrous spherical ZSM-5 aided confinement of Ni particles. Catalytic activity was improved by homogenous distribution of surface acid-basic sites, thereby reducing the propensity of coke deposition. Bimetallic Ni-Ta catalyst produced the highest CH4 and CO2 conversions at 93% and 98%, respectively, with H-2/CO ratio closer to unity (0.97). The nature of acid sites and bimetallic Ni-Ta synergism amplified interaction of catalyst components, resulting in improved interaction with the reactants, thus impeding metal sintering and coke deposition. Consequently, the Ni-Ta/FZSM-5 catalyst shows long-term activity (80 hours) for the DRM reaction at 800 degrees C. Wiley-Blackwell 2020 Article PeerReviewed Hambali, U. and Jalil, A. A. and Abdulrasheed, A. A. and Siang, T. J. and Abdullah, T. A. T. and Ahmad, A. and Vo, D. V. N. (2020) Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance. International Journal of Energy Research, 44 (7). pp. 5696-5712. https://dx.doi.org/10.1002/er.5327 DOI:10.1002/er.5327
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
topic	TP Chemical technology
spellingShingle	TP Chemical technology Hambali, U. Jalil, A. A. Abdulrasheed, A. A. Siang, T. J. Abdullah, T. A. T. Ahmad, A. Vo, D. V. N. Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
description	A highly active and robust fibrous spherical ZSM-5-supported nickel catalyst with different promoters (Mg, Ca, Ta, Ga) have been synthesised by microemulsion method for dry reforming of methane (DRM). The structural framework provided by the unique fibrous spherical ZSM-5 aided confinement of Ni particles. Catalytic activity was improved by homogenous distribution of surface acid-basic sites, thereby reducing the propensity of coke deposition. Bimetallic Ni-Ta catalyst produced the highest CH4 and CO2 conversions at 93% and 98%, respectively, with H-2/CO ratio closer to unity (0.97). The nature of acid sites and bimetallic Ni-Ta synergism amplified interaction of catalyst components, resulting in improved interaction with the reactants, thus impeding metal sintering and coke deposition. Consequently, the Ni-Ta/FZSM-5 catalyst shows long-term activity (80 hours) for the DRM reaction at 800 degrees C.
format	Article
author	Hambali, U. Jalil, A. A. Abdulrasheed, A. A. Siang, T. J. Abdullah, T. A. T. Ahmad, A. Vo, D. V. N.
author_facet	Hambali, U. Jalil, A. A. Abdulrasheed, A. A. Siang, T. J. Abdullah, T. A. T. Ahmad, A. Vo, D. V. N.
author_sort	Hambali, U.
title	Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
title_short	Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
title_full	Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
title_fullStr	Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
title_full_unstemmed	Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
title_sort	fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance
publisher	Wiley-Blackwell
publishDate	2020
url	http://eprints.utm.my/id/eprint/86610/ https://dx.doi.org/10.1002/er.5327
_version_	1680321071039905792
score	13.211869

Fibrous spherical ni-m/zsm-5(m:mg, ca, ta, ga) catalysts for methane dry reforming:the interplay between surface acidity-basicity and coking resistance

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