Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities
The effects of silver nanoparticles (Ag NPs) embedment on the physical and structural characteristics of the holmium ions (Ho3+) activated phosphate-based glass-ceramics were assessed. Two series of such glass-ceramics were prepared using the melt-quenching and characterized. In the first series, th...
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my.utm.865132020-09-30T08:41:18Z http://eprints.utm.my/id/eprint/86513/ Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities Alqarni, A. S. Hussin, R. Alamri, S. N. Ghoshal, S. K. QC Physics The effects of silver nanoparticles (Ag NPs) embedment on the physical and structural characteristics of the holmium ions (Ho3+) activated phosphate-based glass-ceramics were assessed. Two series of such glass-ceramics were prepared using the melt-quenching and characterized. In the first series, the Ag NPs were nucleated from the incorporated AgCl via the redox process. In the second series, the pure Ag nanopowder was directly added. The overall properties of these glass-ceramics were strongly sensitive to the cooling procedure and NPs addition strategies, leading to different density and refractive index modifications in the two series. The recorded O1s XPS peaks were exploited to determine the bridging to non-bridging oxygen ratios in the studied glass-ceramics network that enabled to unfold the differences in the observed inferences. A compelling correlation among various attributes in the achieved glass-ceramics was established. Briefly, the overall traits of the proposed glass-ceramics were tailored by regulating the preparation conditions. Taylor and Francis Ltd. 2020 Article PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/86513/1/AreejSAlqarni2020_CustomizedPhysicalandStructuralFeaturesofPhosphate.pdf Alqarni, A. S. and Hussin, R. and Alamri, S. N. and Ghoshal, S. K. (2020) Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities. Journal of Taibah University for Science, 14 (1). pp. 954-962. https://dx.doi.org/10.1080/16583655.2020.1791536 DOI:10.1080/16583655.2020.1791536 |
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The effects of silver nanoparticles (Ag NPs) embedment on the physical and structural characteristics of the holmium ions (Ho3+) activated phosphate-based glass-ceramics were assessed. Two series of such glass-ceramics were prepared using the melt-quenching and characterized. In the first series, the Ag NPs were nucleated from the incorporated AgCl via the redox process. In the second series, the pure Ag nanopowder was directly added. The overall properties of these glass-ceramics were strongly sensitive to the cooling procedure and NPs addition strategies, leading to different density and refractive index modifications in the two series. The recorded O1s XPS peaks were exploited to determine the bridging to non-bridging oxygen ratios in the studied glass-ceramics network that enabled to unfold the differences in the observed inferences. A compelling correlation among various attributes in the achieved glass-ceramics was established. Briefly, the overall traits of the proposed glass-ceramics were tailored by regulating the preparation conditions. |
format |
Article |
author |
Alqarni, A. S. Hussin, R. Alamri, S. N. Ghoshal, S. K. |
author_facet |
Alqarni, A. S. Hussin, R. Alamri, S. N. Ghoshal, S. K. |
author_sort |
Alqarni, A. S. |
title |
Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
title_short |
Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
title_full |
Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
title_fullStr |
Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
title_full_unstemmed |
Customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
title_sort |
customized physical and structural features of phosphate-based glass-ceramics: role of ag nanoparticles and ho3+ impurities |
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Taylor and Francis Ltd. |
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2020 |
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http://eprints.utm.my/id/eprint/86513/1/AreejSAlqarni2020_CustomizedPhysicalandStructuralFeaturesofPhosphate.pdf http://eprints.utm.my/id/eprint/86513/ https://dx.doi.org/10.1080/16583655.2020.1791536 |
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