A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silico...

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Main Authors: Jilani, Asim, Hussain, Syed Zajif, Othman, Mohd Hafiz Dzarfan, Zulfiqar, Usama, Shakoor, Muhammad Bilal, Khan, Imran Ullah, Iqbal, Javed, Al-Ghamdi, Attieh A., Alshahrie, Ahmed
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Published: Springer Nature B.V. 2018
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Online Access:http://eprints.utm.my/id/eprint/85390/
http://dx.doi.org/10.1007/s10874-018-9376-1
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spelling my.utm.853902020-06-16T06:47:59Z http://eprints.utm.my/id/eprint/85390/ A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia Jilani, Asim Hussain, Syed Zajif Othman, Mohd Hafiz Dzarfan Zulfiqar, Usama Shakoor, Muhammad Bilal Khan, Imran Ullah Iqbal, Javed Al-Ghamdi, Attieh A. Alshahrie, Ahmed Q Science (General) TA Engineering (General). Civil engineering (General) TP Chemical technology In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS. Springer Nature B.V. 2018-09-01 Article PeerReviewed Jilani, Asim and Hussain, Syed Zajif and Othman, Mohd Hafiz Dzarfan and Zulfiqar, Usama and Shakoor, Muhammad Bilal and Khan, Imran Ullah and Iqbal, Javed and Al-Ghamdi, Attieh A. and Alshahrie, Ahmed (2018) A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia. Journal of Atmospheric Chemistry, 75 (3). pp. 271-283. ISSN 0167-7764 http://dx.doi.org/10.1007/s10874-018-9376-1 DOI:10.1007/s10874-018-9376-1
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic Q Science (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
spellingShingle Q Science (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Jilani, Asim
Hussain, Syed Zajif
Othman, Mohd Hafiz Dzarfan
Zulfiqar, Usama
Shakoor, Muhammad Bilal
Khan, Imran Ullah
Iqbal, Javed
Al-Ghamdi, Attieh A.
Alshahrie, Ahmed
A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
description In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.
format Article
author Jilani, Asim
Hussain, Syed Zajif
Othman, Mohd Hafiz Dzarfan
Zulfiqar, Usama
Shakoor, Muhammad Bilal
Khan, Imran Ullah
Iqbal, Javed
Al-Ghamdi, Attieh A.
Alshahrie, Ahmed
author_facet Jilani, Asim
Hussain, Syed Zajif
Othman, Mohd Hafiz Dzarfan
Zulfiqar, Usama
Shakoor, Muhammad Bilal
Khan, Imran Ullah
Iqbal, Javed
Al-Ghamdi, Attieh A.
Alshahrie, Ahmed
author_sort Jilani, Asim
title A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
title_short A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
title_full A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
title_fullStr A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
title_full_unstemmed A comprehensive study on the surface chemistry of particulate matter collected from Jeddah, Saudi Arabia
title_sort comprehensive study on the surface chemistry of particulate matter collected from jeddah, saudi arabia
publisher Springer Nature B.V.
publishDate 2018
url http://eprints.utm.my/id/eprint/85390/
http://dx.doi.org/10.1007/s10874-018-9376-1
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score 13.211869