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Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode

A new electric-field driven extraction approach based on the integration of a bubbleless electrode into the electromembrane extraction (EME) across hollow polymer inclusion membranes (HPIMs) was demonstrated for the first time. The bubbleless electrode was prepared based on an in-situ synthesised po...

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Main Authors: Mamat, N. A., See, H. H.
Format: Article
Published: Elsevier B.V. 2017
Subjects:
QD Chemistry
Online Access:http://eprints.utm.my/id/eprint/76445/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85019064814&doi=10.1016%2fj.chroma.2017.05.005&partnerID=40&md5=5ec0a15c071ddcd090555c250ae869b9
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spelling my.utm.764452018-04-30T13:24:02Z http://eprints.utm.my/id/eprint/76445/ Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode Mamat, N. A. See, H. H. QD Chemistry A new electric-field driven extraction approach based on the integration of a bubbleless electrode into the electromembrane extraction (EME) across hollow polymer inclusion membranes (HPIMs) was demonstrated for the first time. The bubbleless electrode was prepared based on an in-situ synthesised polyacrylamide within a fused silica capillary. The electrode functions as a salt bridge, which conducts the electrical current between the acceptor phase in the lumen of the HPIM and the acceptor solution in the reservoir connected to a high voltage supply through a platinum electrode. Two types of HPIMs were employed, which consisted of desired proportions of cellulose acetate as base polymer, tris(2-ethylhexyl)phosphate as plasticizer, and di-(2-ethylhexyl)phosphoric acid as anionic carrier or Aliquat 336 as cationic carrier, respectively. The EME strategy was evaluated for the simultaneous determination of cationic quaternary ammonium and anionic chlorophenoxy acetic acid herbicides present in the river water, respectively. The analysis was carried out using capillary electrophoresis coupled with UV and contactless conductivity detection. Under the optimised conditions, enrichment factors in the range of 152–185-fold were obtained from 4 mL of river water sample with a 20 min extraction time and an applied voltage of 3000 V. The proposed method provided good linearity with correlation coefficients ranging from 0.9982 to 0.9997 over a concentration range of 1–1000 μg/L. The detection limits of the method for the herbicides were in the range of 0.3–0.4 μg/L, with relative standard deviations of between 4.8% and 8.5%. The relative recoveries obtained when analysing the spiked river water ranged from 99.1% to 100%. A comparison was also made between the newly developed approach with the conventional EME setup by placing the platinum electrode directly in the lumen of the HPIMs. Elsevier B.V. 2017 Article PeerReviewed Mamat, N. A. and See, H. H. (2017) Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode. Journal of Chromatography A, 1504 . pp. 9-16. ISSN 0021-9673 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85019064814&doi=10.1016%2fj.chroma.2017.05.005&partnerID=40&md5=5ec0a15c071ddcd090555c250ae869b9 DOI:10.1016/j.chroma.2017.05.005
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic QD Chemistry
spellingShingle QD Chemistry
Mamat, N. A.
See, H. H.
Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
description A new electric-field driven extraction approach based on the integration of a bubbleless electrode into the electromembrane extraction (EME) across hollow polymer inclusion membranes (HPIMs) was demonstrated for the first time. The bubbleless electrode was prepared based on an in-situ synthesised polyacrylamide within a fused silica capillary. The electrode functions as a salt bridge, which conducts the electrical current between the acceptor phase in the lumen of the HPIM and the acceptor solution in the reservoir connected to a high voltage supply through a platinum electrode. Two types of HPIMs were employed, which consisted of desired proportions of cellulose acetate as base polymer, tris(2-ethylhexyl)phosphate as plasticizer, and di-(2-ethylhexyl)phosphoric acid as anionic carrier or Aliquat 336 as cationic carrier, respectively. The EME strategy was evaluated for the simultaneous determination of cationic quaternary ammonium and anionic chlorophenoxy acetic acid herbicides present in the river water, respectively. The analysis was carried out using capillary electrophoresis coupled with UV and contactless conductivity detection. Under the optimised conditions, enrichment factors in the range of 152–185-fold were obtained from 4 mL of river water sample with a 20 min extraction time and an applied voltage of 3000 V. The proposed method provided good linearity with correlation coefficients ranging from 0.9982 to 0.9997 over a concentration range of 1–1000 μg/L. The detection limits of the method for the herbicides were in the range of 0.3–0.4 μg/L, with relative standard deviations of between 4.8% and 8.5%. The relative recoveries obtained when analysing the spiked river water ranged from 99.1% to 100%. A comparison was also made between the newly developed approach with the conventional EME setup by placing the platinum electrode directly in the lumen of the HPIMs.
format Article
author Mamat, N. A.
See, H. H.
author_facet Mamat, N. A.
See, H. H.
author_sort Mamat, N. A.
title Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
title_short Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
title_full Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
title_fullStr Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
title_full_unstemmed Simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
title_sort simultaneous electromembrane extraction of cationic and anionic herbicides across hollow polymer inclusion membranes with a bubbleless electrode
publisher Elsevier B.V.
publishDate 2017
url http://eprints.utm.my/id/eprint/76445/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85019064814&doi=10.1016%2fj.chroma.2017.05.005&partnerID=40&md5=5ec0a15c071ddcd090555c250ae869b9
_version_ 1643657312317997056
score 13.211869

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