Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles

A series of tellurite (TeO2) glass containing samarium (Sm2O3) and silver nanoparticles with a composition of (89.6-x)TeO2-10MgO-(x)Sm2O3-0.4AgCl with 0.2 ≤ x ≤ 1.0 mol% have been synthesized by a conventional melt quenching technique. The X-ray diffraction pattern verified the amorphous nature of g...

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Main Authors: Yusoff, N. M., Sahar, M. R.
Format: Conference or Workshop Item
Published: Trans Tech Publications Ltd 2016
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Online Access:http://eprints.utm.my/id/eprint/73606/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84959875595&doi=10.4028%2fwww.scientific.net%2fMSF.846.107&partnerID=40&md5=f16f302d550bf4f961e805dcef4880ba
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spelling my.utm.736062017-11-20T08:43:00Z http://eprints.utm.my/id/eprint/73606/ Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles Yusoff, N. M. Sahar, M. R. QC Physics A series of tellurite (TeO2) glass containing samarium (Sm2O3) and silver nanoparticles with a composition of (89.6-x)TeO2-10MgO-(x)Sm2O3-0.4AgCl with 0.2 ≤ x ≤ 1.0 mol% have been synthesized by a conventional melt quenching technique. The X-ray diffraction pattern verified the amorphous nature of glasses. A systematic study on the relationship between Sm2O3 concentration and the physical properties of the glass has been made. The effect on the progressive replacement of TeO2 by Sm2O3 on density, molar volume, refractive index and electronic polarizability has been investigated. The results show that density and ionic packing density are in the range of 4.91-5.04 g cm-3 and 0.444 – 0.455, respectively, increases as the amount of Sm2O3 is increased up to 0.8 mol% and decrease afterward. However, the molar volume which is in between, 29.59-30.26 m3 mol-1 decreasing as the amount of Sm2O3 is increased up to 0.8 mol% and increase thereafter. Meanwhile the refractive index which is deduced from optical energy band gap is found to possess a value in the range of 2.37 to 2.45 and electronic polarizability is in the range of 7.14-7.51Å3. All the results will be discussed with respect to the modification in glass composition. Trans Tech Publications Ltd 2016 Conference or Workshop Item PeerReviewed Yusoff, N. M. and Sahar, M. R. (2016) Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles. In: 28th Regional Conference on Solid State Science and Technology, RCSSST 2014, 25 - 27 Nov 2014, Pahang, Malaysia. https://www.scopus.com/inward/record.uri?eid=2-s2.0-84959875595&doi=10.4028%2fwww.scientific.net%2fMSF.846.107&partnerID=40&md5=f16f302d550bf4f961e805dcef4880ba
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic QC Physics
spellingShingle QC Physics
Yusoff, N. M.
Sahar, M. R.
Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
description A series of tellurite (TeO2) glass containing samarium (Sm2O3) and silver nanoparticles with a composition of (89.6-x)TeO2-10MgO-(x)Sm2O3-0.4AgCl with 0.2 ≤ x ≤ 1.0 mol% have been synthesized by a conventional melt quenching technique. The X-ray diffraction pattern verified the amorphous nature of glasses. A systematic study on the relationship between Sm2O3 concentration and the physical properties of the glass has been made. The effect on the progressive replacement of TeO2 by Sm2O3 on density, molar volume, refractive index and electronic polarizability has been investigated. The results show that density and ionic packing density are in the range of 4.91-5.04 g cm-3 and 0.444 – 0.455, respectively, increases as the amount of Sm2O3 is increased up to 0.8 mol% and decrease afterward. However, the molar volume which is in between, 29.59-30.26 m3 mol-1 decreasing as the amount of Sm2O3 is increased up to 0.8 mol% and increase thereafter. Meanwhile the refractive index which is deduced from optical energy band gap is found to possess a value in the range of 2.37 to 2.45 and electronic polarizability is in the range of 7.14-7.51Å3. All the results will be discussed with respect to the modification in glass composition.
format Conference or Workshop Item
author Yusoff, N. M.
Sahar, M. R.
author_facet Yusoff, N. M.
Sahar, M. R.
author_sort Yusoff, N. M.
title Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
title_short Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
title_full Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
title_fullStr Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
title_full_unstemmed Effect of Sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
title_sort effect of sm3+ concentration on physical properties of magnesium tellurite glasses containing silver nanoparticles
publisher Trans Tech Publications Ltd
publishDate 2016
url http://eprints.utm.my/id/eprint/73606/
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84959875595&doi=10.4028%2fwww.scientific.net%2fMSF.846.107&partnerID=40&md5=f16f302d550bf4f961e805dcef4880ba
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score 13.211869