Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Published: |
Springer
2008
|
| Subjects: | |
| Online Access: | http://eprints.utm.my/id/eprint/7321/ http://dx.doi.org/10.1007/s10562-008-9727-7 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts. |
|---|