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Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol

Epoxy resins are among the basic components for coatings manufacture but because of their cost and environment effects, some environmental protection regulations have restricted the use of chemicals considered toxic. The potential of using phenolic rich fractions of bio-oil derived from the pyrolysi...

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Main Authors: Ahmed, Murtala Musa, Nasri, Noor Shawal, Mohsin, Rahmat, Hamza, Usman Dadum, Mohammed, Jibril
Format: Article
Published: Trans Tech Publications 2014
Subjects:
TN Mining engineering. Metallurgy
Online Access:http://eprints.utm.my/id/eprint/62318/
http://dx.doi.org/10.4028/www.scientific.net/AMM.554.101
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spelling my.utm.623182017-06-05T03:19:09Z http://eprints.utm.my/id/eprint/62318/ Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol Ahmed, Murtala Musa Nasri, Noor Shawal Mohsin, Rahmat Hamza, Usman Dadum Mohammed, Jibril TN Mining engineering. Metallurgy Epoxy resins are among the basic components for coatings manufacture but because of their cost and environment effects, some environmental protection regulations have restricted the use of chemicals considered toxic. The potential of using phenolic rich fractions of bio-oil derived from the pyrolysis of a sustainable agricultural waste for epoxy resin synthesis was investigated. Epoxy resins with different concentration of water-insoluble heavy fraction were synthesized. The bio-oil, heavy fraction and prepared resins were later characterized using Fourier Transform Infra- Red (FTIR), Gas Chromatography Mass Spectrometry (GC-MS) and Differential Scanning Calorimetry (DSC). FTIR and GC-MS results confirmed the presence of phenols on both the bio-oil and heavy fraction with heavy fraction having a higher concentration. DSC analysis showed a corresponding increase on curing time of the resins with increased quantity of phenolic rich components. FTIR analysis of the resin indicated high-ortho structure. Utilization of bio-oil as a source of phenol for epoxy resins manufacture would significantly reduce the cost and negative environmental effects of the current resins. Trans Tech Publications 2014 Article PeerReviewed Ahmed, Murtala Musa and Nasri, Noor Shawal and Mohsin, Rahmat and Hamza, Usman Dadum and Mohammed, Jibril (2014) Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol. Applied Mechanics and Materials, 554 . pp. 101-105. ISSN 1660-9336 http://dx.doi.org/10.4028/www.scientific.net/AMM.554.101 DOI:10.4028/www.scientific.net/AMM.554.101
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TN Mining engineering. Metallurgy
spellingShingle TN Mining engineering. Metallurgy
Ahmed, Murtala Musa
Nasri, Noor Shawal
Mohsin, Rahmat
Hamza, Usman Dadum
Mohammed, Jibril
Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
description Epoxy resins are among the basic components for coatings manufacture but because of their cost and environment effects, some environmental protection regulations have restricted the use of chemicals considered toxic. The potential of using phenolic rich fractions of bio-oil derived from the pyrolysis of a sustainable agricultural waste for epoxy resin synthesis was investigated. Epoxy resins with different concentration of water-insoluble heavy fraction were synthesized. The bio-oil, heavy fraction and prepared resins were later characterized using Fourier Transform Infra- Red (FTIR), Gas Chromatography Mass Spectrometry (GC-MS) and Differential Scanning Calorimetry (DSC). FTIR and GC-MS results confirmed the presence of phenols on both the bio-oil and heavy fraction with heavy fraction having a higher concentration. DSC analysis showed a corresponding increase on curing time of the resins with increased quantity of phenolic rich components. FTIR analysis of the resin indicated high-ortho structure. Utilization of bio-oil as a source of phenol for epoxy resins manufacture would significantly reduce the cost and negative environmental effects of the current resins.
format Article
author Ahmed, Murtala Musa
Nasri, Noor Shawal
Mohsin, Rahmat
Hamza, Usman Dadum
Mohammed, Jibril
author_facet Ahmed, Murtala Musa
Nasri, Noor Shawal
Mohsin, Rahmat
Hamza, Usman Dadum
Mohammed, Jibril
author_sort Ahmed, Murtala Musa
title Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
title_short Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
title_full Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
title_fullStr Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
title_full_unstemmed Preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
title_sort preparation of epoxy-novolac resin binder using phenolic rich fractions of biomass pyrolytic oil as partial substitute of phenol
publisher Trans Tech Publications
publishDate 2014
url http://eprints.utm.my/id/eprint/62318/
http://dx.doi.org/10.4028/www.scientific.net/AMM.554.101
_version_ 1643655381825617920
score 13.211869

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