Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles

Fe3O4 magnetic nanoparticles (MNPs) synthesized in-housed using co-precipitation method was assessed for the treatment of synthetic aqueous solutions contaminated by Cu(II) ions. Experimental results showed that at 25ºC, the optimum value for Cu(II) removal was pH 6.0 and an adsorbent dose of 60.0 m...

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Main Authors: Abd. Ali, Layth Imad, Wan Ibrahim, Wan Aini, Sulaiman, Azli
Format: Conference or Workshop Item
Language:English
Published: 2014
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Online Access:http://eprints.utm.my/id/eprint/61323/1/WanAiniWan2014_AdsorptionStudiesforRemovalofTraceCopperMetal.pdf
http://eprints.utm.my/id/eprint/61323/
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spelling my.utm.613232017-03-30T06:29:24Z http://eprints.utm.my/id/eprint/61323/ Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles Abd. Ali, Layth Imad Wan Ibrahim, Wan Aini Sulaiman, Azli QD Chemistry Fe3O4 magnetic nanoparticles (MNPs) synthesized in-housed using co-precipitation method was assessed for the treatment of synthetic aqueous solutions contaminated by Cu(II) ions. Experimental results showed that at 25ºC, the optimum value for Cu(II) removal was pH 6.0 and an adsorbent dose of 60.0 mg. The adsorption capacity of Fe3O4 nanoparticles for Cu(II) is 16.28 mg g-1. Adsorption kinetic rates were found to be fast; total equilibrium was achieved after 180 min. Kinetic experimental data fitted very well the pseudo-second order equation and the value of adsorption rate constants was calculated to be 0.0006 and 0.0013 g mg-1 min at 5 and 40 mg L-1 initial Cu(II) concentrations, respectively. The equilibrium isotherms were evaluated in terms of maximum adsorption capacity and adsorption affinity by the application of Langmuir and Freundlich equations. Results indicate that the Langmuir model fits adsorption isotherm data better than the Freundlich model. 2014 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/61323/1/WanAiniWan2014_AdsorptionStudiesforRemovalofTraceCopperMetal.pdf Abd. Ali, Layth Imad and Wan Ibrahim, Wan Aini and Sulaiman, Azli (2014) Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles. In: Proceeding of 2nd International Science Postgraduate Conference (ISPC2014), 10-12 Mac, 2014, Skudai, Johor.
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic QD Chemistry
spellingShingle QD Chemistry
Abd. Ali, Layth Imad
Wan Ibrahim, Wan Aini
Sulaiman, Azli
Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
description Fe3O4 magnetic nanoparticles (MNPs) synthesized in-housed using co-precipitation method was assessed for the treatment of synthetic aqueous solutions contaminated by Cu(II) ions. Experimental results showed that at 25ºC, the optimum value for Cu(II) removal was pH 6.0 and an adsorbent dose of 60.0 mg. The adsorption capacity of Fe3O4 nanoparticles for Cu(II) is 16.28 mg g-1. Adsorption kinetic rates were found to be fast; total equilibrium was achieved after 180 min. Kinetic experimental data fitted very well the pseudo-second order equation and the value of adsorption rate constants was calculated to be 0.0006 and 0.0013 g mg-1 min at 5 and 40 mg L-1 initial Cu(II) concentrations, respectively. The equilibrium isotherms were evaluated in terms of maximum adsorption capacity and adsorption affinity by the application of Langmuir and Freundlich equations. Results indicate that the Langmuir model fits adsorption isotherm data better than the Freundlich model.
format Conference or Workshop Item
author Abd. Ali, Layth Imad
Wan Ibrahim, Wan Aini
Sulaiman, Azli
author_facet Abd. Ali, Layth Imad
Wan Ibrahim, Wan Aini
Sulaiman, Azli
author_sort Abd. Ali, Layth Imad
title Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
title_short Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
title_full Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
title_fullStr Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
title_full_unstemmed Adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
title_sort adsorption studies for removal of trace copper metal ions from aqueous samples using magnetic nanoparticles
publishDate 2014
url http://eprints.utm.my/id/eprint/61323/1/WanAiniWan2014_AdsorptionStudiesforRemovalofTraceCopperMetal.pdf
http://eprints.utm.my/id/eprint/61323/
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score 13.211869