Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications

The effect of zinc borate (ZB) quantity on the mechanical and dielectric properties of 20 phr magnesium oxide/10 % rubbers (9/1 NR/ENR-50)/metallocene linear low-density polyethylene (mLLDPE) in the presence of N,N-m-phenylene bismaleimide (HVA-2) compatibilizer was investigated for wire and cable a...

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Main Authors: Alwaan, Ismaeel, Hassan, Azman, M. Piah, M. Afendi
Format: Article
Published: Springer-Verlag London Ltd 2015
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Online Access:http://eprints.utm.my/id/eprint/58402/
http://dx.doi.org/10.1007/s13726-015-0319-2
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spelling my.utm.584022021-12-07T00:29:43Z http://eprints.utm.my/id/eprint/58402/ Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications Alwaan, Ismaeel Hassan, Azman M. Piah, M. Afendi TP Chemical technology The effect of zinc borate (ZB) quantity on the mechanical and dielectric properties of 20 phr magnesium oxide/10 % rubbers (9/1 NR/ENR-50)/metallocene linear low-density polyethylene (mLLDPE) in the presence of N,N-m-phenylene bismaleimide (HVA-2) compatibilizer was investigated for wire and cable applications. With the increase in ZB loading, the tensile strength and the elongation-at-break of the composites decreased while the tensile modulus increased. In all composites, the strain-induced crystallization phenomenon at 200 % elongation was being observed in the stress–strain curves. Moreover, the dielectric strength, dielectric loss, permittivity and volume resistivity at frequency of 50 Hz were investigated. The permittivity of all composites increased with a rise in the voltage within the range of 1–5 kV. The loading of ZB in the composites improved the permittivity and volume resistivity as compared to the neat mLLDPE. The dielectric loss increased and 2 phr ZB composite displayed the highest dielectric loss among all other composites. On the other hand, the breakdown decreased with increasing ZB loading and the highest breakdown was observed in the 6 phr ZB composite. It was concluded that all composites are suitable for wire and cable application and the best result based on dielectric properties was observed in the 6 phr ZB composite. Springer-Verlag London Ltd 2015 Article PeerReviewed Alwaan, Ismaeel and Hassan, Azman and M. Piah, M. Afendi (2015) Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications. Iranian Polymer Journal, 24 (4). pp. 279-288. ISSN 1026-1265 http://dx.doi.org/10.1007/s13726-015-0319-2 DOI:10.1007/s13726-015-0319-2
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Alwaan, Ismaeel
Hassan, Azman
M. Piah, M. Afendi
Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
description The effect of zinc borate (ZB) quantity on the mechanical and dielectric properties of 20 phr magnesium oxide/10 % rubbers (9/1 NR/ENR-50)/metallocene linear low-density polyethylene (mLLDPE) in the presence of N,N-m-phenylene bismaleimide (HVA-2) compatibilizer was investigated for wire and cable applications. With the increase in ZB loading, the tensile strength and the elongation-at-break of the composites decreased while the tensile modulus increased. In all composites, the strain-induced crystallization phenomenon at 200 % elongation was being observed in the stress–strain curves. Moreover, the dielectric strength, dielectric loss, permittivity and volume resistivity at frequency of 50 Hz were investigated. The permittivity of all composites increased with a rise in the voltage within the range of 1–5 kV. The loading of ZB in the composites improved the permittivity and volume resistivity as compared to the neat mLLDPE. The dielectric loss increased and 2 phr ZB composite displayed the highest dielectric loss among all other composites. On the other hand, the breakdown decreased with increasing ZB loading and the highest breakdown was observed in the 6 phr ZB composite. It was concluded that all composites are suitable for wire and cable application and the best result based on dielectric properties was observed in the 6 phr ZB composite.
format Article
author Alwaan, Ismaeel
Hassan, Azman
M. Piah, M. Afendi
author_facet Alwaan, Ismaeel
Hassan, Azman
M. Piah, M. Afendi
author_sort Alwaan, Ismaeel
title Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
title_short Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
title_full Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
title_fullStr Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
title_full_unstemmed Effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
title_sort effect of zinc borate on mechanical and dielectric properties of metallocene linear low-density polyethylene/rubbers/magnesium oxide composite for wire and cable applications
publisher Springer-Verlag London Ltd
publishDate 2015
url http://eprints.utm.my/id/eprint/58402/
http://dx.doi.org/10.1007/s13726-015-0319-2
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score 13.211869