Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms

Utilization of nanoparticles (NPs) for a broad range of applications has caused considerable quantities of these materials to be released into the environment. Issues of how and where the NPs are distributed into the subsurface aquatic environments are questions for those in environmental engineerin...

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Main Authors: Bayat, Ali Esfandyari, Junin, Radzuan, Mohsin, Rahmat, Hokmabadi, Mehrdad, Shamshirband, Shahaboddin
Format: Article
Published: Kluwer Academic Publishers 2015
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Online Access:http://eprints.utm.my/id/eprint/55841/
http://dx.doi.org/10.1007/s11051-015-3031-4
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spelling my.utm.558412017-02-15T01:02:19Z http://eprints.utm.my/id/eprint/55841/ Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms Bayat, Ali Esfandyari Junin, Radzuan Mohsin, Rahmat Hokmabadi, Mehrdad Shamshirband, Shahaboddin TP Chemical technology Utilization of nanoparticles (NPs) for a broad range of applications has caused considerable quantities of these materials to be released into the environment. Issues of how and where the NPs are distributed into the subsurface aquatic environments are questions for those in environmental engineering. This study investigated the influence of three abundant clay minerals namely kaolinite, montmorillonite, and illite in the subsurface natural aquatic systems on the transport and retention of aluminum oxide (Al2O3, 40 nm) and titanium dioxide (TiO2, 10–30 nm) NPs through saturated limestone porous media. The clay concentrations in porous media were set at 2 and 4 vol% of the holder capacity. Breakthrough curves in the columns outlets were measured using a UV–Vis spectrophotometer. It was found that the maximum NPs recoveries were obtained when there was no clay particle in the porous medium. On the other hand, increase in concentration of clay particles has resulted in the NPs recoveries being significantly declined. Due to fibrous structure of illite, it was found to be more effective for NPs retention in comparison to montmorillonite and kaolinite. Overall, the position of clay particles in the porous media pores and their morphologies were found to be two main reasons for increase of NPs retention in porous media Kluwer Academic Publishers 2015-05 Article PeerReviewed Bayat, Ali Esfandyari and Junin, Radzuan and Mohsin, Rahmat and Hokmabadi, Mehrdad and Shamshirband, Shahaboddin (2015) Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms. Journal of Nanoparticle Research, 17 (5). pp. 1-14. ISSN 1388-0764 http://dx.doi.org/10.1007/s11051-015-3031-4 DOI:10.1007/s11051-015-3031-4
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Bayat, Ali Esfandyari
Junin, Radzuan
Mohsin, Rahmat
Hokmabadi, Mehrdad
Shamshirband, Shahaboddin
Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
description Utilization of nanoparticles (NPs) for a broad range of applications has caused considerable quantities of these materials to be released into the environment. Issues of how and where the NPs are distributed into the subsurface aquatic environments are questions for those in environmental engineering. This study investigated the influence of three abundant clay minerals namely kaolinite, montmorillonite, and illite in the subsurface natural aquatic systems on the transport and retention of aluminum oxide (Al2O3, 40 nm) and titanium dioxide (TiO2, 10–30 nm) NPs through saturated limestone porous media. The clay concentrations in porous media were set at 2 and 4 vol% of the holder capacity. Breakthrough curves in the columns outlets were measured using a UV–Vis spectrophotometer. It was found that the maximum NPs recoveries were obtained when there was no clay particle in the porous medium. On the other hand, increase in concentration of clay particles has resulted in the NPs recoveries being significantly declined. Due to fibrous structure of illite, it was found to be more effective for NPs retention in comparison to montmorillonite and kaolinite. Overall, the position of clay particles in the porous media pores and their morphologies were found to be two main reasons for increase of NPs retention in porous media
format Article
author Bayat, Ali Esfandyari
Junin, Radzuan
Mohsin, Rahmat
Hokmabadi, Mehrdad
Shamshirband, Shahaboddin
author_facet Bayat, Ali Esfandyari
Junin, Radzuan
Mohsin, Rahmat
Hokmabadi, Mehrdad
Shamshirband, Shahaboddin
author_sort Bayat, Ali Esfandyari
title Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
title_short Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
title_full Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
title_fullStr Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
title_full_unstemmed Influence of clay particles on Al2O3 and TiO2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
title_sort influence of clay particles on al2o3 and tio2 nanoparticles transport and retention through limestone porous media: measurements and mechanisms
publisher Kluwer Academic Publishers
publishDate 2015
url http://eprints.utm.my/id/eprint/55841/
http://dx.doi.org/10.1007/s11051-015-3031-4
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score 13.211869