Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads

The management of radioactive wastes is receiving much attention because radioactive wastes are a threat to people and environment. Cesium which is a component of nuclear waste contributes to water pollution. In this research, maghemite nanoparticles was prepared by the chemical co-precipitation of...

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主要な著者: Majidnia, Zohreh, Idris, Ani
フォーマット: 論文
出版事項: Elsevier 2015
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オンライン・アクセス:http://eprints.utm.my/id/eprint/55086/
http://dx.doi.org/10.1016/j.cej.2014.09.118
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spelling my.utm.550862017-02-15T07:34:15Z http://eprints.utm.my/id/eprint/55086/ Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads Majidnia, Zohreh Idris, Ani TP Chemical technology The management of radioactive wastes is receiving much attention because radioactive wastes are a threat to people and environment. Cesium which is a component of nuclear waste contributes to water pollution. In this research, maghemite nanoparticles was prepared by the chemical co-precipitation of Fe2+ and Fe3+ and embedded in PVA and alginate matrix and then used in the removal of Cs+ from the aqueous solution. Several parameters like pH, contact time and initial ion concentration were varied so as to determine its influence on the adsorption performance. The findings revealed that Cs+ was removed rapidly under sunlight; where 70% was removed during the first 30min and finally 91% of Cs ions was removed after 300min, hence the term photoadsorption best described its mechanism. Several adsorption kinetic models such as Langmuir and Freundlich isotherm equation, pseudo first-order and pseudo second order were then used to describe the photoadsorption of Cs (I). After photo adsorption the maghemite PVA-alginate beads can be easily isolated from aqueous solution by means of a magnet and reused for at least eight times without losing its initial properties. Elsevier 2015-02 Article PeerReviewed Majidnia, Zohreh and Idris, Ani (2015) Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads. Chemical Engineering Journal, 262 . pp. 372-382. ISSN 1385-8947 http://dx.doi.org/10.1016/j.cej.2014.09.118 DOI:10.1016/j.cej.2014.09.118
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Majidnia, Zohreh
Idris, Ani
Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
description The management of radioactive wastes is receiving much attention because radioactive wastes are a threat to people and environment. Cesium which is a component of nuclear waste contributes to water pollution. In this research, maghemite nanoparticles was prepared by the chemical co-precipitation of Fe2+ and Fe3+ and embedded in PVA and alginate matrix and then used in the removal of Cs+ from the aqueous solution. Several parameters like pH, contact time and initial ion concentration were varied so as to determine its influence on the adsorption performance. The findings revealed that Cs+ was removed rapidly under sunlight; where 70% was removed during the first 30min and finally 91% of Cs ions was removed after 300min, hence the term photoadsorption best described its mechanism. Several adsorption kinetic models such as Langmuir and Freundlich isotherm equation, pseudo first-order and pseudo second order were then used to describe the photoadsorption of Cs (I). After photo adsorption the maghemite PVA-alginate beads can be easily isolated from aqueous solution by means of a magnet and reused for at least eight times without losing its initial properties.
format Article
author Majidnia, Zohreh
Idris, Ani
author_facet Majidnia, Zohreh
Idris, Ani
author_sort Majidnia, Zohreh
title Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
title_short Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
title_full Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
title_fullStr Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
title_full_unstemmed Evaluation of cesium removal from radioactive waste water using maghemite PVA-alginate beads
title_sort evaluation of cesium removal from radioactive waste water using maghemite pva-alginate beads
publisher Elsevier
publishDate 2015
url http://eprints.utm.my/id/eprint/55086/
http://dx.doi.org/10.1016/j.cej.2014.09.118
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