Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites
This paper reported the effects of increasing Hibiscus canttabinus fiber (also known as kenaf fiber) loading level on properties of electron beam irradiated polylactic acid/low density polyethylene (PLA/LDPE). PLA and LDPE were compounded with 5-20 parts per hundred resins (phr) of kenaf respectivel...
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my.utm.549642017-07-31T07:00:37Z http://eprints.utm.my/id/eprint/54964/ Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites Soo, Tueen Bee Lee, Tin Sin Ratnam, Chantara Thevy Kavee-Raaz, R. R. D. Tiam, Ting Tee David, Hui Rahmat, Abdul Razak TP Chemical technology This paper reported the effects of increasing Hibiscus canttabinus fiber (also known as kenaf fiber) loading level on properties of electron beam irradiated polylactic acid/low density polyethylene (PLA/LDPE). PLA and LDPE were compounded with 5-20 parts per hundred resins (phr) of kenaf respectively to enhance mechanical properties. The compounded kenaf added PLA/LDPE samples were electron beam irradiated from 15 to 60 kGy. The physical properties of kenaf added PLA/LDPE samples were characterized using gel content, X-Ray diffraction and scanning electron microscopy analysis. The results showed that the increasing of irradiation dosages in PLA/LDPE have gradually increased the gel content and tensile strength due to the formation of crosslinking networks in polymer matrix. However, the higher loading level of kenaf and irradiation dosages could decrease the elongation at break of PLA/LDPE samples. This is due to the restriction of polymer chains mobility as resulted by the poor interfacial adhesion between polymer matrix and kenaf particles as well as the formation of crosslinking networks in polymer matrix limits the sliding of polymer chains. Meanwhile, the increasing of kenaf loading level also has gradually increased the crystallinity of PLA/LDPE matrix. It is concluded that the electron beam irradiation dosages and amount of kenaf fiber in PLA/LDPE matrix should be kept at maximum 45 kGy and 15 phr, respectively for better combination to enhance the properties of the composites. Elsevier 2015-09 Article PeerReviewed Soo, Tueen Bee and Lee, Tin Sin and Ratnam, Chantara Thevy and Kavee-Raaz, R. R. D. and Tiam, Ting Tee and David, Hui and Rahmat, Abdul Razak (2015) Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites. Composites Part B-Engineering, 79 . pp. 35-46. ISSN 1879-1069 http://dx.doi.org/10.1016/j.compositesb.2015.04.019 DOI:10.1016/j.compositesb.2015.04.019 |
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TP Chemical technology Soo, Tueen Bee Lee, Tin Sin Ratnam, Chantara Thevy Kavee-Raaz, R. R. D. Tiam, Ting Tee David, Hui Rahmat, Abdul Razak Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
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This paper reported the effects of increasing Hibiscus canttabinus fiber (also known as kenaf fiber) loading level on properties of electron beam irradiated polylactic acid/low density polyethylene (PLA/LDPE). PLA and LDPE were compounded with 5-20 parts per hundred resins (phr) of kenaf respectively to enhance mechanical properties. The compounded kenaf added PLA/LDPE samples were electron beam irradiated from 15 to 60 kGy. The physical properties of kenaf added PLA/LDPE samples were characterized using gel content, X-Ray diffraction and scanning electron microscopy analysis. The results showed that the increasing of irradiation dosages in PLA/LDPE have gradually increased the gel content and tensile strength due to the formation of crosslinking networks in polymer matrix. However, the higher loading level of kenaf and irradiation dosages could decrease the elongation at break of PLA/LDPE samples. This is due to the restriction of polymer chains mobility as resulted by the poor interfacial adhesion between polymer matrix and kenaf particles as well as the formation of crosslinking networks in polymer matrix limits the sliding of polymer chains. Meanwhile, the increasing of kenaf loading level also has gradually increased the crystallinity of PLA/LDPE matrix. It is concluded that the electron beam irradiation dosages and amount of kenaf fiber in PLA/LDPE matrix should be kept at maximum 45 kGy and 15 phr, respectively for better combination to enhance the properties of the composites. |
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Article |
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Soo, Tueen Bee Lee, Tin Sin Ratnam, Chantara Thevy Kavee-Raaz, R. R. D. Tiam, Ting Tee David, Hui Rahmat, Abdul Razak |
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Soo, Tueen Bee Lee, Tin Sin Ratnam, Chantara Thevy Kavee-Raaz, R. R. D. Tiam, Ting Tee David, Hui Rahmat, Abdul Razak |
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Soo, Tueen Bee |
title |
Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
title_short |
Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
title_full |
Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
title_fullStr |
Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
title_full_unstemmed |
Electron beam irradiation enhanced of Hibiscus cannabinus fiber strengthen polylactic acid composites |
title_sort |
electron beam irradiation enhanced of hibiscus cannabinus fiber strengthen polylactic acid composites |
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Elsevier |
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2015 |
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http://eprints.utm.my/id/eprint/54964/ http://dx.doi.org/10.1016/j.compositesb.2015.04.019 |
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